Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897590816> ?p ?o ?g. }
- W2897590816 endingPage "113" @default.
- W2897590816 startingPage "107" @default.
- W2897590816 abstract "Abstract Copper-ethylene ion-molecule complexes are produced by laser vaporization of a copper rod in a pulsed supersonic expansion of ethylene and argon. The ions are mass selected and studied via infrared laser photodissociation spectroscopy in the C H stretching region (2600–3400 cm−1). Argon tagging is employed to study the spectra of the n = 1–3 complexes. Spectra of complexes containing four to nine ligands are measured by the elimination of ethylene. Density functional theory calculations are carried out in support of the experimental spectroscopy. The symmetric C H stretches of a free ethylene were found to red shift by about 30 cm−1 in the spectra of Cu+(C2H4) and Cu+(C2H4)2. Cu+(C2H4)3 is found to represent a fully- coordinated copper cation. Its C H stretches are found to blue shift by 10 to 20 cm−1 as a result of steric crowding. In larger complexes, the three-coordinate core ion incorporates additional ethylene solvent molecules through cation-π and CH-π interactions. These weak interactions only slightly perturb the vibrations of the external ligands." @default.
- W2897590816 created "2018-10-26" @default.
- W2897590816 creator A5025449262 @default.
- W2897590816 creator A5075462093 @default.
- W2897590816 creator A5085502223 @default.
- W2897590816 date "2019-01-01" @default.
- W2897590816 modified "2023-10-17" @default.
- W2897590816 title "Infrared spectroscopy of coordination and solvation in Cu+(C2H4)n (n = 1–9) complexes" @default.
- W2897590816 cites W1647669015 @default.
- W2897590816 cites W1667999265 @default.
- W2897590816 cites W1968120538 @default.
- W2897590816 cites W1968954676 @default.
- W2897590816 cites W1976823654 @default.
- W2897590816 cites W1991203297 @default.
- W2897590816 cites W1992320249 @default.
- W2897590816 cites W1995533549 @default.
- W2897590816 cites W1998090485 @default.
- W2897590816 cites W1999233351 @default.
- W2897590816 cites W2000176377 @default.
- W2897590816 cites W2005404721 @default.
- W2897590816 cites W2007483167 @default.
- W2897590816 cites W2019118473 @default.
- W2897590816 cites W2026109388 @default.
- W2897590816 cites W2028268476 @default.
- W2897590816 cites W2042925035 @default.
- W2897590816 cites W2056254910 @default.
- W2897590816 cites W2056940253 @default.
- W2897590816 cites W2073753357 @default.
- W2897590816 cites W2074070768 @default.
- W2897590816 cites W2080030733 @default.
- W2897590816 cites W2081050298 @default.
- W2897590816 cites W2089440895 @default.
- W2897590816 cites W2091620915 @default.
- W2897590816 cites W2130718600 @default.
- W2897590816 cites W2137439986 @default.
- W2897590816 cites W2145640410 @default.
- W2897590816 cites W2154508485 @default.
- W2897590816 cites W2159556073 @default.
- W2897590816 cites W2169144836 @default.
- W2897590816 cites W2170592654 @default.
- W2897590816 cites W2176997977 @default.
- W2897590816 cites W2184193065 @default.
- W2897590816 cites W2316018931 @default.
- W2897590816 cites W2418077897 @default.
- W2897590816 cites W2421475969 @default.
- W2897590816 cites W2427322902 @default.
- W2897590816 cites W2464029424 @default.
- W2897590816 cites W2469282651 @default.
- W2897590816 cites W2469948086 @default.
- W2897590816 cites W2470696087 @default.
- W2897590816 cites W2514989373 @default.
- W2897590816 cites W2516858657 @default.
- W2897590816 cites W2556309208 @default.
- W2897590816 cites W2583267334 @default.
- W2897590816 cites W2766991095 @default.
- W2897590816 cites W282630728 @default.
- W2897590816 cites W289360464 @default.
- W2897590816 cites W575648279 @default.
- W2897590816 doi "https://doi.org/10.1016/j.ijms.2018.10.008" @default.
- W2897590816 hasPublicationYear "2019" @default.
- W2897590816 type Work @default.
- W2897590816 sameAs 2897590816 @default.
- W2897590816 citedByCount "10" @default.
- W2897590816 countsByYear W28975908162019 @default.
- W2897590816 countsByYear W28975908162020 @default.
- W2897590816 countsByYear W28975908162021 @default.
- W2897590816 countsByYear W28975908162022 @default.
- W2897590816 countsByYear W28975908162023 @default.
- W2897590816 crossrefType "journal-article" @default.
- W2897590816 hasAuthorship W2897590816A5025449262 @default.
- W2897590816 hasAuthorship W2897590816A5075462093 @default.
- W2897590816 hasAuthorship W2897590816A5085502223 @default.
- W2897590816 hasBestOaLocation W28975908161 @default.
- W2897590816 hasConcept C120665830 @default.
- W2897590816 hasConcept C121332964 @default.
- W2897590816 hasConcept C145148216 @default.
- W2897590816 hasConcept C148093993 @default.
- W2897590816 hasConcept C153642686 @default.
- W2897590816 hasConcept C158355884 @default.
- W2897590816 hasConcept C178790620 @default.
- W2897590816 hasConcept C185592680 @default.
- W2897590816 hasConcept C32891209 @default.
- W2897590816 hasConcept C544153396 @default.
- W2897590816 hasConcept C62520636 @default.
- W2897590816 hasConcept C68913812 @default.
- W2897590816 hasConceptScore W2897590816C120665830 @default.
- W2897590816 hasConceptScore W2897590816C121332964 @default.
- W2897590816 hasConceptScore W2897590816C145148216 @default.
- W2897590816 hasConceptScore W2897590816C148093993 @default.
- W2897590816 hasConceptScore W2897590816C153642686 @default.
- W2897590816 hasConceptScore W2897590816C158355884 @default.
- W2897590816 hasConceptScore W2897590816C178790620 @default.
- W2897590816 hasConceptScore W2897590816C185592680 @default.
- W2897590816 hasConceptScore W2897590816C32891209 @default.
- W2897590816 hasConceptScore W2897590816C544153396 @default.
- W2897590816 hasConceptScore W2897590816C62520636 @default.
- W2897590816 hasConceptScore W2897590816C68913812 @default.
- W2897590816 hasFunder F4320338279 @default.