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- W2897623237 endingPage "6900" @default.
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- W2897623237 abstract "A catalytic enantioselective conjugate addition with commercially available allenylboronic acid pinacol ester as nucleophile promoted by a chiral copper complex of N-heterocyclic carbene (NHC) is disclosed. This process constitutes an unprecedented instance of the conjugate addition that introduces an allenyl group into α,β-unsaturated carbonyl compounds, affording products that are otherwise difficult to access in up to 92% yield, >98% allenyl addition selectivity and 96:4 enantiomeric ratio. DFT calculations were performed to elucidate the origins of enantioselectivity." @default.
- W2897623237 created "2018-10-26" @default.
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- W2897623237 date "2018-10-16" @default.
- W2897623237 modified "2023-10-17" @default.
- W2897623237 title "N-Heterocyclic Carbene–Cu-Catalyzed Enantioselective Allenyl Conjugate Addition" @default.
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- W2897623237 doi "https://doi.org/10.1021/acs.orglett.8b03029" @default.
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