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- W2897675373 abstract "We have previously reported that the palladium-catalyzed cross-coupling reaction of air-stable potassium alkenyltrifluoroborates with aryl halides and triflates proceeds readily with good yields. Recent progress in outlining the scope and limitations of such reactions is described herein. The palladium-catalyzed cross-coupling reaction of potassium alkenyltrifluoroborates with aryl and heteroaryl halides and triflates proceeds readily with moderate to excellent yields. The alkenyl cross-coupling reaction can generally be effected using 2 mol % of PdCl2(dppf).CH2Cl2 as catalyst in i-PrOH-H2O in the presence of t-BuNH2 as the base. A variety of functional groups are tolerated in both partners, and the process is stereospecific with regard to the alkenyltrifluoroborate starting material." @default.
- W2897675373 created "2018-10-26" @default.
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- W2897675373 date "2002-10-30" @default.
- W2897675373 modified "2023-09-23" @default.
- W2897675373 title "Suzuki−Miyaura Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates" @default.
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- W2897675373 doi "https://doi.org/10.1021/jo026236y" @default.
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