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• W2897780228 abstract "Carbon nanotubes help nickel work in water Most synthetic chemistry takes place in hydrocarbon-derived solvents. By contrast, enzymes manage to perform exquisitely selective reactions in water, often by surrounding reactants with hydrophobic pockets. Kitanosono et al. show that single-walled carbon nanotubes can similarly render simple nickel catalysts effective in water. Integration of the nickel ions with chiral ligands and surfactants at the nanotube surface produces a highly enantioselective catalyst for nitrone formation from aldoximes and unsaturated ketones. Spectroscopy suggests that the nanotubes enhance electron density at the nickel center as well as provide a hydrophobic milieu. Science , this issue p. 311" @default.
• W2897780228 created "2018-10-26" @default.
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• W2897780228 date "2018-10-19" @default.
• W2897780228 modified "2023-10-16" @default.
• W2897780228 title "Chiral Lewis acids integrated with single-walled carbon nanotubes for asymmetric catalysis in water" @default.
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• W2897780228 doi "https://doi.org/10.1126/science.aap7883" @default.
• W2897780228 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30337405" @default.
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