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- W2897780512 abstract "1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadiene is an effective silyl transfer reagent towards the oxygen of nitrate coordinated to Cr(iii) in a pincer complex. Two nitrate oxygens are removed to give the 17 valence electron octahedral complex (H2L)Cr(NO3)2(NO). This is shown by a variety of spectroscopic methods, together with DFT, to be a Cr(i) complex with a linear CrNO unit. This work also identifies future applications of this reductive silylation process." @default.
- W2897780512 created "2018-10-26" @default.
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- W2897780512 date "2019-01-01" @default.
- W2897780512 modified "2023-10-14" @default.
- W2897780512 title "Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation" @default.
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- W2897780512 doi "https://doi.org/10.1039/c8sc02979b" @default.
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