Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897784481> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2897784481 endingPage "7" @default.
- W2897784481 startingPage "2" @default.
- W2897784481 abstract "Abstract The effect of alcohol structure on photocatalytic production of H2 from C-3 alcohols was studied on 0.5% Pt/TiO2. A C-2 alcohol (ethanol) was also included for comparative purposes. For individual reactions from 10% v/v aqueous solutions of alcohols, hydrogen production followed the order ethanol ≈ propan-2-ol > propan-1-ol > propane-1,2,3-triol > propane-1,2-diol > propane-1,3-diol. The process was found to be quite sensitive to the presence of additional alcohols in the reaction medium, as evidenced by competitive reactions. Therefore, propan-2-ol conversion was retarded in the presence of traces of the other alcohols, this effect being particularly significant for vicinal diols. Additional experiments showed that adsorption of alcohols on Pt/TiO2 followed the order propane-1,2,3-triol > propane-1,2-diol > propane-1,3-diol > propan-1-ol > ethanol > propan-2-ol. Adsorption studies (DRIFT) and monitoring of reaction products showed that the main photocatalyzed process for propan-2-ol and propan-1-ol transformation is dehydrogenation to the corresponding carbonyl compound (especially for propan-2-ol both in the liquid and the gas phase). In the case of liquid-phase transformation of propan-1-ol, ethane was also detected which is indicative of the dissociative mechanism to lead to the corresponding C-1 alkane. All in all, competitive reactions proved to be very useful for mechanistic studies." @default.
- W2897784481 created "2018-10-26" @default.
- W2897784481 creator A5015755370 @default.
- W2897784481 creator A5026213871 @default.
- W2897784481 creator A5036078053 @default.
- W2897784481 creator A5039374205 @default.
- W2897784481 creator A5044747959 @default.
- W2897784481 creator A5056380561 @default.
- W2897784481 date "2019-05-01" @default.
- W2897784481 modified "2023-10-17" @default.
- W2897784481 title "Photocatalytic production of hydrogen from binary mixtures of C-3 alcohols on Pt/TiO2: Influence of alcohol structure" @default.
- W2897784481 cites W1011972049 @default.
- W2897784481 cites W2004924439 @default.
- W2897784481 cites W2042492216 @default.
- W2897784481 cites W2050207489 @default.
- W2897784481 cites W2065750769 @default.
- W2897784481 cites W2066078143 @default.
- W2897784481 cites W2071706572 @default.
- W2897784481 cites W2080095158 @default.
- W2897784481 cites W2089914045 @default.
- W2897784481 cites W2314443527 @default.
- W2897784481 cites W2319952155 @default.
- W2897784481 cites W2465209202 @default.
- W2897784481 cites W2471028471 @default.
- W2897784481 cites W2520603260 @default.
- W2897784481 cites W2577569319 @default.
- W2897784481 cites W2593817004 @default.
- W2897784481 cites W2621747449 @default.
- W2897784481 cites W2760043263 @default.
- W2897784481 cites W2781641812 @default.
- W2897784481 cites W771522245 @default.
- W2897784481 cites W874941520 @default.
- W2897784481 doi "https://doi.org/10.1016/j.cattod.2018.10.001" @default.
- W2897784481 hasPublicationYear "2019" @default.
- W2897784481 type Work @default.
- W2897784481 sameAs 2897784481 @default.
- W2897784481 citedByCount "14" @default.
- W2897784481 countsByYear W28977844812019 @default.
- W2897784481 countsByYear W28977844812020 @default.
- W2897784481 countsByYear W28977844812021 @default.
- W2897784481 countsByYear W28977844812022 @default.
- W2897784481 countsByYear W28977844812023 @default.
- W2897784481 crossrefType "journal-article" @default.
- W2897784481 hasAuthorship W2897784481A5015755370 @default.
- W2897784481 hasAuthorship W2897784481A5026213871 @default.
- W2897784481 hasAuthorship W2897784481A5036078053 @default.
- W2897784481 hasAuthorship W2897784481A5039374205 @default.
- W2897784481 hasAuthorship W2897784481A5044747959 @default.
- W2897784481 hasAuthorship W2897784481A5056380561 @default.
- W2897784481 hasBestOaLocation W28977844811 @default.
- W2897784481 hasConcept C114157696 @default.
- W2897784481 hasConcept C161790260 @default.
- W2897784481 hasConcept C178790620 @default.
- W2897784481 hasConcept C179104552 @default.
- W2897784481 hasConcept C185592680 @default.
- W2897784481 hasConcept C202189072 @default.
- W2897784481 hasConcept C2781066024 @default.
- W2897784481 hasConcept C33923547 @default.
- W2897784481 hasConcept C48372109 @default.
- W2897784481 hasConcept C512968161 @default.
- W2897784481 hasConcept C65165184 @default.
- W2897784481 hasConcept C94375191 @default.
- W2897784481 hasConceptScore W2897784481C114157696 @default.
- W2897784481 hasConceptScore W2897784481C161790260 @default.
- W2897784481 hasConceptScore W2897784481C178790620 @default.
- W2897784481 hasConceptScore W2897784481C179104552 @default.
- W2897784481 hasConceptScore W2897784481C185592680 @default.
- W2897784481 hasConceptScore W2897784481C202189072 @default.
- W2897784481 hasConceptScore W2897784481C2781066024 @default.
- W2897784481 hasConceptScore W2897784481C33923547 @default.
- W2897784481 hasConceptScore W2897784481C48372109 @default.
- W2897784481 hasConceptScore W2897784481C512968161 @default.
- W2897784481 hasConceptScore W2897784481C65165184 @default.
- W2897784481 hasConceptScore W2897784481C94375191 @default.
- W2897784481 hasFunder F4320310214 @default.
- W2897784481 hasFunder F4320320300 @default.
- W2897784481 hasFunder F4320321595 @default.
- W2897784481 hasFunder F4320335598 @default.
- W2897784481 hasLocation W28977844811 @default.
- W2897784481 hasOpenAccess W2897784481 @default.
- W2897784481 hasPrimaryLocation W28977844811 @default.
- W2897784481 hasRelatedWork W1972847525 @default.
- W2897784481 hasRelatedWork W1978820613 @default.
- W2897784481 hasRelatedWork W2006471732 @default.
- W2897784481 hasRelatedWork W2120625591 @default.
- W2897784481 hasRelatedWork W2147427301 @default.
- W2897784481 hasRelatedWork W2339877473 @default.
- W2897784481 hasRelatedWork W3135125188 @default.
- W2897784481 hasRelatedWork W4214810971 @default.
- W2897784481 hasRelatedWork W4214867964 @default.
- W2897784481 hasRelatedWork W4307000173 @default.
- W2897784481 hasVolume "328" @default.
- W2897784481 isParatext "false" @default.
- W2897784481 isRetracted "false" @default.
- W2897784481 magId "2897784481" @default.
- W2897784481 workType "article" @default.