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• W2897791275 abstract "The new chiral PNP pincer ligand N2,N6-bis((3aR, 8aR)-2,2-dimethyl-4,4,8,8-tetraphenyltetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)pyridine-2,6-diamine (PNP-TADDOL) was synthesized in 80% isolated yield. Complexes of the type [M(PNP-TADDOL)(CO)3] (M = Cr, Mo, and W) were prepared via a solvothermal approach. This methodology constitutes a fast, simple, and practical synthetic method to obtain complexes of that type in high isolated yields. The X-ray structure of the molybdenum complex is presented." @default.
• W2897791275 created "2018-10-26" @default.
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• W2897791275 date "2018-10-20" @default.
• W2897791275 modified "2023-10-15" @default.
• W2897791275 title "Synthesis and characterization of TADDOL-based chiral group six PNP pincer tricarbonyl complexes" @default.
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• W2897791275 doi "https://doi.org/10.1007/s00706-018-2281-0" @default.
• W2897791275 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6320742" @default.
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