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- W2897791535 abstract "All-solid-state lithium (Li) ion batteries are regarded as optimal solutions to secure energy problems because of their characteristics, such as no leakage and nonflammability. However, low Li-ion conductivity in these batteries limits their applications. Perovskite-type Li-ion conductors have been considered promising solid electrolytes by replacing A- and B-site ions to improve ion conductivity. In this study, the strategy of replacing O2- anions with F- in perovskite-type structure LiSr1−0.5xTiTaO6−xFx was carried out. Solid electrolytes were successfully prepared by conventional solid-state reactions. The influence of fluorine ion (F-) content in these compounds was systematically investigated regarding ion conductivity. Total conductivity attained was as high as 3.67 × 10−4 S·cm−1 at room temperature in samples with x = 0.1. However, excessive F- doping causes octahedral distortions and produced narrow bottlenecks surrounded by [TiO6] octahedra, which led to decreased conductivity and increased migration activation energy." @default.
- W2897791535 created "2018-10-26" @default.
- W2897791535 creator A5041060928 @default.
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- W2897791535 date "2019-02-01" @default.
- W2897791535 modified "2023-09-23" @default.
- W2897791535 title "Perovskite-type compounds in anion-substituted LiSr1−0.5xTiTaO6−xFx electrolyte for improving lithium-ion conduction" @default.
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- W2897791535 doi "https://doi.org/10.1016/j.ceramint.2018.10.156" @default.
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