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• W2897831288 abstract "A novel zirconium(IV)-substituted tetramer polyoxotungstate, H 6 K 4 Na 16 [Zr 4 (β-GeW 10 O 38 ) 2 (A-α-PW 9 O 34 ) 2 ]·37H 2 O, was synthesized hydrothermally and characterized by IR spectroscopy, elemental analysis, thermogravimetric analysis, powder X-ray diffraction, energy-dispersive X-ray spectroscopy and single-crystal X-ray diffraction. The compound crystallizes in the monoclinic P 2/ n space group. The most remarkable feature is that the centrosymmetric Zr-based polyoxotungstate tetramer consists of dilacunary Keggin-type germanotungstate and trilacunary Keggin-type phosphotungstate units that are linked by Zr IV ions." @default.
• W2897831288 created "2018-10-26" @default.
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• W2897831288 date "2018-10-17" @default.
• W2897831288 modified "2023-10-04" @default.
• W2897831288 title "An unprecedented Zr-containing polyoxometalate tetramer with mixed trilacunary/dilacunary Keggin-type polyoxotungstate units" @default.
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• W2897831288 doi "https://doi.org/10.1107/s2053229618006538" @default.
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