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• W2897832086 abstract "This paper describes instrumentation of a spectrophotometric system and its application for in-situ, real-time measurement of adsorption thermodynamics in aqueous solution by use of laboratory-constructed fiber-optic measurements. A measurement vessel was assembled from an adsorption bag, stirring and thermostatic devices, and a fiber-optic dipping probe. A macroporous adsorption resin and rutin were selected as the model adsorbent and adsorbate. In-situ liquid phase adsorption measurement of the system was achieved through monitoring of the absorption by dipping the probe in a broad range of concentrations. In-situ measurement of the AB-8 resin adsorption at temperatures from 303 K to 323 K was systematically carried out, showing that temperature was an influencing factor for the adsorption capacity and initial adsorption rate. The adsorption thermodynamic parameters for AB-8 indicated that the results well fitted the Freundlich model. In addition, a favorable, exothermic, spontaneous, physical process of rutin was demonstrated on AB-8. The obtained results showed that this method was successful at keeping the adsorption temperature constant. The application of fiber-optic sensing to the in-situ measurement of liquid phase adsorption enables automated and real-time monitoring of adsorption thermodynamics." @default.
• W2897832086 created "2018-10-26" @default.
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• W2897832086 date "2018-10-16" @default.
• W2897832086 modified "2023-10-16" @default.
• W2897832086 title "In-situ measurement of the adsorption thermodynamics of rutin on macroporous adsorption resins by fiber-optic sensing" @default.
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• W2897832086 doi "https://doi.org/10.1080/10739149.2018.1505636" @default.
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