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• W2897863252 abstract "Functional self-assemblies derived from noncovalent interactions such as lipid vesicles and DNA chiral double helices are a typical feature of natural life activity. Because of this phenomenon, a self-assembly approach for various functional organic particles is a desirable objective in supramolecular chemistry. Here, we report the discovery of enantiomeric conformers from a twisted macrocyclic host (MH), which was obtained from an achiral precursor by Schiff base reaction. Further studies suggest that a series of unexpected and stable core-shell-based organic micro/nanospheres can be directly precipitated from a simple reaction solution with high yield. A single-crystal X-ray diffraction analysis of MH revealed that the unusual C-H···π interaction triggered self-assembly of the enantiomeric forms in the solid state plays an important role in the formation of the core-shell-shaped organic particles." @default.
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• W2897863252 date "2019-01-01" @default.
• W2897863252 modified "2023-10-12" @default.
• W2897863252 title "Organic core–shell-shaped micro/nanoparticles from twisted macrocycles in Schiff base reaction" @default.
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• W2897863252 doi "https://doi.org/10.1039/c8sc03824d" @default.
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