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- W2897873880 abstract "The title sulfoxide, C 18 H 20 O 2 S, was prepared by controlled oxidation of thia -Dianin's compound using hydrogen peroxide in glacial acetic acid. On recrystallization from glacial acetic acid, it was found to form unsolvated, spontaneously resolved crystals, the initial crystal structure analysis revealing the presence of both sulfoxide epimers in the crystal. On multiple recrystallization a single epimer was observed, with crystallization occurring in the unchanged orthorhombic space group P 2 1 2 1 2 1 , with Z′ = 1. The molecule possesses a distal conformation, referring to the juxtaposition of the p -hydoxyphenyl substituent with respect to its syn- related methyl group, with the sulfoxide oxygen atom anti to the aromatic substituent. The molecular packing features O—H...O hydrogen bond chains running parallel to the b axis of the unit cell." @default.
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- W2897873880 date "2018-10-19" @default.
- W2897873880 modified "2023-09-24" @default.
- W2897873880 title "The first spontaneous resolution of a sulfoxide: Dianin's compound analogue, (R)-4-(4-hydroxyphenyl)-2,2,4-trimethylthiachroman-1-oxide" @default.
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- W2897873880 doi "https://doi.org/10.1107/s2056989018014366" @default.
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