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• W2897876576 startingPage "147" @default.
• W2897876576 abstract "In this study, three types of fluorinated polyacrylates (PBFB, PBFS, and PMFA) were synthesized by 4-gem-bis(2,2,3,3,4,4,5,5,5-nonafluoropentyl)-1-butene, 4-gem-bis(2,2,3,3,4,4,5,5,5-nonafluoropentyl)-methine-1-styrene, and 3,3,4,4,5,5,6,6,6-nonafluorohexyl acrylate, respectively, as monomers via emulsion polymerization. Particle size, particle size distribution, and zeta potential were tested to assess the emulsion stability. Afterwards, the latexes were coated onto fabrics to obtain gem-bis(fluoroalkyl)-cotton. The surface properties of the treated cotton fabrics were analyzed by X-ray photoelectron spectroscopy and water contact angle. It was found that, when controlling the fluorine content level to be similar, the water contact angles of gem-bis(fluoroalkyl)-cottons were 127° ± 0.5° and 134.9° ± 0.7°, respectively, which were both higher than that of mono-fluoroalkyl-cotton (PMFA-cotton of 125.2° ± 0.2°). This showed that gem-bis-fluoroalkyl groups could provide better hydrophobic performance than the mono-fluoroalkyl group, especially when the rigid benzene was used as a side-chain bridged group." @default.
• W2897876576 created "2018-10-26" @default.
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• W2897876576 date "2019-02-01" @default.
• W2897876576 modified "2023-09-26" @default.
• W2897876576 title "Preparation of fluoropolymer with gem-bis-fluoroalkylated side-chain and its application on cotton fabric finishing" @default.
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• W2897876576 doi "https://doi.org/10.1139/cjc-2017-0761" @default.
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