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- W2897877963 abstract "Abstract A three‐component cyclization of 2‐methylquinolines, trimethylsilyl cyanide, and alkylamines or α‐amino acids mediated by CuSO 4 was developed. By employing oxygen as the clean oxidant, cyanated imidazo[1,5‐a]quinolines were constructed with high efficiency for the first time. The loading of CuSO 4 could be lowered to 20 mol% with a slightly diminished yield. The synthetic utility of this method is further highlighted by the gram‐scale synthesis and tolerance of sensitive functional group. magnified image" @default.
- W2897877963 created "2018-10-26" @default.
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- W2897877963 date "2018-11-14" @default.
- W2897877963 modified "2023-10-18" @default.
- W2897877963 title "Synthesis of Cyanide-Functionalized Imidazo[1,5-a]quinolines via Copper-Mediated Aerobic Three-Component Cyclizations" @default.
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- W2897877963 doi "https://doi.org/10.1002/adsc.201801060" @default.
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