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• W2897904064 abstract "Abstract Mössbauer spectroscopy is a microscopic element‐specific technique that is a well‐established tool for probing aspects of electronic structure, especially those reflected in magnetic properties. Even though the properties of a sample material may well depend on long‐range behavior, Mössbauer spectroscopy does not require the probe atoms or nuclei to be polarized and it hence can be performed in zero applied field. Even so, special external conditions such as high pressure, high magnetic fields, or ultralow temperatures are fairly easily applied. The most distinctive feature of Mössbauer spectroscopy is the possibility to gain rather direct information on the charge state of the resonant atom via the so‐called isomer shift. The needed information is gained by determination of hyperfine interaction energies, that is, the coupling between the electron shell and its nucleus. The signal is given only by solid materials; however, they need not be crystalline, meaning that glasses, frozen solutions, and amorphous solids can be studied. Two examples are presented to demonstrate the power of Mössbauer spectroscopy in the study of magnetic and electronic properties of materials with 5f‐electrons. Both of them are counterparts of superconducting materials. NpFeAsO is a counterpart of a rare‐earth iron oxypnictide, and NpTGa 5 is a counterpart of the plutonium superconductor PuCoGa 5 ." @default.
• W2897904064 created "2018-10-26" @default.
• W2897904064 creator A5064384509 @default.
• W2897904064 date "2018-06-21" @default.
• W2897904064 modified "2023-10-15" @default.
• W2897904064 title "<scp>M</scp>össbauer Spectroscopy of Actinide Compounds" @default.
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• W2897904064 doi "https://doi.org/10.1002/9781119951438.eibc2538" @default.
• W2897904064 hasPublicationYear "2018" @default.
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