Matches in SemOpenAlex for { <https://semopenalex.org/work/W2897943681> ?p ?o ?g. }
- W2897943681 endingPage "16524" @default.
- W2897943681 startingPage "16520" @default.
- W2897943681 abstract "Palladium-catalyzed allylic alkylation of nonstabilized carbon nucleophiles is difficult and remains a major challenge. Reported here is a highly chemo- and regioselective direct palladium-catalyzed C-allylation of hydrazones, generated from carbonyls, as a source of umpolung unstabilized alkyl carbanions and surrogates of alkyl organometallic reagents. Contrary to classical allylation techniques, this umpolung reaction utilizes hydrazones prepared not only from aryl aldehydes but also from alkyl aldehydes and ketones as renewable feedstocks. This strategy complements the palladium-catalyzed coupling of unstabilized nucleophiles with allylic electrophiles by providing an efficient and selective catalytic alternative to the traditional use of highly reactive alkyl organometallic reagents." @default.
- W2897943681 created "2018-10-26" @default.
- W2897943681 creator A5005753434 @default.
- W2897943681 creator A5017745007 @default.
- W2897943681 creator A5052111964 @default.
- W2897943681 creator A5075046462 @default.
- W2897943681 creator A5079912108 @default.
- W2897943681 date "2018-11-14" @default.
- W2897943681 modified "2023-09-29" @default.
- W2897943681 title "Umpolung of Carbonyl Groups as Alkyl Organometallic Reagent Surrogates for Palladium-Catalyzed Allylic Alkylation" @default.
- W2897943681 cites W1536994479 @default.
- W2897943681 cites W1964622031 @default.
- W2897943681 cites W1970357928 @default.
- W2897943681 cites W1972331349 @default.
- W2897943681 cites W1974807453 @default.
- W2897943681 cites W1977662913 @default.
- W2897943681 cites W1977868435 @default.
- W2897943681 cites W1979350834 @default.
- W2897943681 cites W1986001811 @default.
- W2897943681 cites W1986445339 @default.
- W2897943681 cites W1988323627 @default.
- W2897943681 cites W1998079750 @default.
- W2897943681 cites W1999475521 @default.
- W2897943681 cites W2007814829 @default.
- W2897943681 cites W2010398507 @default.
- W2897943681 cites W2010878369 @default.
- W2897943681 cites W2017772177 @default.
- W2897943681 cites W2018745205 @default.
- W2897943681 cites W2019237825 @default.
- W2897943681 cites W2024184423 @default.
- W2897943681 cites W2028406649 @default.
- W2897943681 cites W2031192939 @default.
- W2897943681 cites W2031991029 @default.
- W2897943681 cites W2032622166 @default.
- W2897943681 cites W2035586374 @default.
- W2897943681 cites W2036758375 @default.
- W2897943681 cites W2040166991 @default.
- W2897943681 cites W2044661599 @default.
- W2897943681 cites W2049095005 @default.
- W2897943681 cites W2058456312 @default.
- W2897943681 cites W2067498652 @default.
- W2897943681 cites W2072591300 @default.
- W2897943681 cites W2076193722 @default.
- W2897943681 cites W2081248392 @default.
- W2897943681 cites W2082572449 @default.
- W2897943681 cites W2089038808 @default.
- W2897943681 cites W2089361684 @default.
- W2897943681 cites W2089659231 @default.
- W2897943681 cites W2093131029 @default.
- W2897943681 cites W2096353395 @default.
- W2897943681 cites W2096631577 @default.
- W2897943681 cites W2097129068 @default.
- W2897943681 cites W2099348802 @default.
- W2897943681 cites W2103380929 @default.
- W2897943681 cites W2104718876 @default.
- W2897943681 cites W2113664842 @default.
- W2897943681 cites W2113684570 @default.
- W2897943681 cites W2114136593 @default.
- W2897943681 cites W2114949212 @default.
- W2897943681 cites W2123499342 @default.
- W2897943681 cites W2131614569 @default.
- W2897943681 cites W2135286812 @default.
- W2897943681 cites W2137686743 @default.
- W2897943681 cites W2141626852 @default.
- W2897943681 cites W2143678407 @default.
- W2897943681 cites W2146559302 @default.
- W2897943681 cites W2153866464 @default.
- W2897943681 cites W2155583674 @default.
- W2897943681 cites W2165550844 @default.
- W2897943681 cites W2166289193 @default.
- W2897943681 cites W2167829310 @default.
- W2897943681 cites W2195645900 @default.
- W2897943681 cites W2285277827 @default.
- W2897943681 cites W2312711615 @default.
- W2897943681 cites W2314827084 @default.
- W2897943681 cites W2319679993 @default.
- W2897943681 cites W2326550954 @default.
- W2897943681 cites W2331433565 @default.
- W2897943681 cites W2333968900 @default.
- W2897943681 cites W2499895154 @default.
- W2897943681 cites W2517648757 @default.
- W2897943681 cites W2523126741 @default.
- W2897943681 cites W2549858613 @default.
- W2897943681 cites W2560245593 @default.
- W2897943681 cites W2560300306 @default.
- W2897943681 cites W2561153739 @default.
- W2897943681 cites W2588692903 @default.
- W2897943681 cites W2761222859 @default.
- W2897943681 cites W2784728005 @default.
- W2897943681 cites W2801309297 @default.
- W2897943681 cites W2802736712 @default.
- W2897943681 cites W2807228829 @default.
- W2897943681 cites W2808310004 @default.
- W2897943681 cites W28516499 @default.
- W2897943681 cites W2952055687 @default.
- W2897943681 cites W2952466398 @default.
- W2897943681 cites W4231485760 @default.
- W2897943681 cites W4237096166 @default.