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- W2897949559 abstract "Abstract We investigated the hydration of hydrophobic epoxides and alkynes in water using 24 types of heterogeneous and homogeneous catalysts and found that Hbeta (Hβ) zeolite with a relatively high Si/Al ratio (Si/Al = 75), Hβ-75, is an effective catalyst. Hβ-75 showed wide substrate scope, good reusability, and applicability in gram-scale synthesis for both types of reactions. The effects of hydrophobicity, acidity, and the size of zeolite pores were also comprehensively studied through the hydration of hydrophilic and hydrophobic epoxides and alkynes with different molecular sizes using two types of zeolite (Hβ and HZSM5). The high yields obtained using the Hβ-75 catalyst in the hydration of hydrophobic epoxides and alkynes are attributed to the hydrophobic interaction between zeolite pores with the substrates, as well as the relatively large pore size." @default.
- W2897949559 created "2018-10-26" @default.
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- W2897949559 date "2018-12-01" @default.
- W2897949559 modified "2023-10-17" @default.
- W2897949559 title "High-silica Hβ zeolites for catalytic hydration of hydrophobic epoxides and alkynes in water" @default.
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- W2897949559 doi "https://doi.org/10.1016/j.jcat.2018.10.004" @default.
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