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- W2897977812 abstract "The novel and effective diastereoselective synthesis of multifunctionalized dihydropyridones, including CF3-substituted derivatives, has been developed on the basis of the piperidine-promoted domino reaction of carbamoylated enaminones with aldehydes. The products have been prepared in 38-90% yields and can be easily isolated by crystallization. Tautomerism, epimerization, and atropisomerism of dihydropyridones have been studied. The use of the resulting dihydropyridones in the synthesis of 1,2,6-trisubstituted 4-pyridone-3-carboxamides has been demonstrated via oxidative aromatization initiated by iodine." @default.
- W2897977812 created "2018-10-26" @default.
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- W2897977812 date "2018-10-18" @default.
- W2897977812 modified "2023-09-24" @default.
- W2897977812 title "Synthesis of Multifunctionalized 2,3-Dihydro-4-pyridones and 4-Pyridones via the Reaction of Carbamoylated Enaminones with Aldehydes" @default.
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- W2897977812 doi "https://doi.org/10.1021/acs.joc.8b02075" @default.
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