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- W2898022892 abstract "Diglycerol obtained from biomass glycerol has been valorized into selective products by acetalization reaction in the presence of ZnCl2. A synthesis method of monoacetals via catalyst-transfer is carried out encompassing two phase-separated reagents, diglycerol with n-octanal. Mechanistic analysis has revealed that the formation of unstable emulsion promotes the reaction, and the selectivity is affected by the catalyst-transfer direction. By measuring the Zn content in the two phases, we demonstrated the transfer direction of ZnCl2 and the monoacetal were opposite, resulting in separation of the catalyst and the substrate. And the formation of diacetal was retarded. The products monoacetals exhibit superior surfactant properties, especially in terms of foam stability and alkali tolerance." @default.
- W2898022892 created "2018-10-26" @default.
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- W2898022892 date "2018-10-15" @default.
- W2898022892 modified "2023-10-18" @default.
- W2898022892 title "Selective Synthesis of Diglycerol Monoacetals via Catalyst-Transfer in Biphasic System and Assessment of their Surfactant Properties" @default.
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- W2898022892 doi "https://doi.org/10.1021/acssuschemeng.8b04082" @default.
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