Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898029664> ?p ?o ?g. }
- W2898029664 endingPage "13849" @default.
- W2898029664 startingPage "13837" @default.
- W2898029664 abstract "Silicon photocathodes coated with drop-casted {Mo3S4}-based polyoxothiometalate assemblies are demonstrated to be effective for sunlight-driven hydrogen evolution reaction (HER) in acid conditions. These photocathodes are catalytically more efficient than that coated with the parent thiomolybdate incorporating an organic ligand, as supported by a higher onset potential and a lower overvoltage at 10 mA cm–2. At pH 7.3, the trend is inversed and the beneficial effect of the polyoxometalate for the HER is not observed. Moreover, the polyoxothiometalate-modified photocathode is found to be also more stable under acid conditions and can be operated at the light-limited catalytic current for more than 40 h. Furthermore, X-ray photoelectron spectroscopy and atomic force microscopy measurements indicate that the cathodic polarization of both photocathodes leads to the release of a large amount of the deposited material into the electrolyte solution concomitantly with the formation of mixed valence species {Mo(IV)3–xMo(III)xO4–nSn}(4–x)+ resulting from the replacement of S2– sulfido ligands in the cluster by oxo O2– groups; these combined effects are shown to be beneficial for the photoelectrocatalysis." @default.
- W2898029664 created "2018-10-26" @default.
- W2898029664 creator A5000329880 @default.
- W2898029664 creator A5008002948 @default.
- W2898029664 creator A5051191290 @default.
- W2898029664 creator A5056086116 @default.
- W2898029664 creator A5058497329 @default.
- W2898029664 creator A5059471132 @default.
- W2898029664 creator A5078964964 @default.
- W2898029664 creator A5083051142 @default.
- W2898029664 creator A5085769645 @default.
- W2898029664 date "2018-10-22" @default.
- W2898029664 modified "2023-10-13" @default.
- W2898029664 title "Polyoxothiometalate-Derivatized Silicon Photocathodes for Sunlight-Driven Hydrogen Evolution Reaction" @default.
- W2898029664 cites W1679184796 @default.
- W2898029664 cites W1971113415 @default.
- W2898029664 cites W1974896731 @default.
- W2898029664 cites W1979728399 @default.
- W2898029664 cites W1982685288 @default.
- W2898029664 cites W1984746972 @default.
- W2898029664 cites W1986829915 @default.
- W2898029664 cites W1987933164 @default.
- W2898029664 cites W1990520496 @default.
- W2898029664 cites W1990676753 @default.
- W2898029664 cites W1992935731 @default.
- W2898029664 cites W1994945623 @default.
- W2898029664 cites W1995461813 @default.
- W2898029664 cites W1995879477 @default.
- W2898029664 cites W1996542847 @default.
- W2898029664 cites W2002898819 @default.
- W2898029664 cites W2004421078 @default.
- W2898029664 cites W2008577434 @default.
- W2898029664 cites W2013142118 @default.
- W2898029664 cites W2013516496 @default.
- W2898029664 cites W2016739489 @default.
- W2898029664 cites W2027960382 @default.
- W2898029664 cites W2030129549 @default.
- W2898029664 cites W2035805541 @default.
- W2898029664 cites W2040634925 @default.
- W2898029664 cites W2042189655 @default.
- W2898029664 cites W2043775186 @default.
- W2898029664 cites W2044413365 @default.
- W2898029664 cites W2047120282 @default.
- W2898029664 cites W2066655134 @default.
- W2898029664 cites W2073086715 @default.
- W2898029664 cites W2081432965 @default.
- W2898029664 cites W2082231829 @default.
- W2898029664 cites W2087072090 @default.
- W2898029664 cites W2088401654 @default.
- W2898029664 cites W2092562792 @default.
- W2898029664 cites W2093290670 @default.
- W2898029664 cites W2093539930 @default.
- W2898029664 cites W2100951188 @default.
- W2898029664 cites W2105378649 @default.
- W2898029664 cites W2112672275 @default.
- W2898029664 cites W2121379638 @default.
- W2898029664 cites W2129100328 @default.
- W2898029664 cites W2129328881 @default.
- W2898029664 cites W2131366083 @default.
- W2898029664 cites W2139056417 @default.
- W2898029664 cites W2139088889 @default.
- W2898029664 cites W2143456478 @default.
- W2898029664 cites W2144332006 @default.
- W2898029664 cites W2144882045 @default.
- W2898029664 cites W2149246887 @default.
- W2898029664 cites W2150950804 @default.
- W2898029664 cites W2161568713 @default.
- W2898029664 cites W2172184044 @default.
- W2898029664 cites W2253268763 @default.
- W2898029664 cites W2265465406 @default.
- W2898029664 cites W2283290883 @default.
- W2898029664 cites W2295124316 @default.
- W2898029664 cites W2330613123 @default.
- W2898029664 cites W2332448579 @default.
- W2898029664 cites W2334461736 @default.
- W2898029664 cites W2488937128 @default.
- W2898029664 cites W2546612054 @default.
- W2898029664 cites W2566029125 @default.
- W2898029664 cites W2614957700 @default.
- W2898029664 cites W2757322416 @default.
- W2898029664 cites W2765454013 @default.
- W2898029664 cites W2782864119 @default.
- W2898029664 cites W827230869 @default.
- W2898029664 doi "https://doi.org/10.1021/acsomega.8b01734" @default.
- W2898029664 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6645094" @default.
- W2898029664 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31458082" @default.
- W2898029664 hasPublicationYear "2018" @default.
- W2898029664 type Work @default.
- W2898029664 sameAs 2898029664 @default.
- W2898029664 citedByCount "12" @default.
- W2898029664 countsByYear W28980296642019 @default.
- W2898029664 countsByYear W28980296642020 @default.
- W2898029664 countsByYear W28980296642021 @default.
- W2898029664 countsByYear W28980296642022 @default.
- W2898029664 countsByYear W28980296642023 @default.
- W2898029664 crossrefType "journal-article" @default.
- W2898029664 hasAuthorship W2898029664A5000329880 @default.
- W2898029664 hasAuthorship W2898029664A5008002948 @default.