Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898036501> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W2898036501 abstract "The infinite dilution activity coefficients gamma(i), partial molar excess enthalpies H(i)EBAR and entropies S(i)EBAR of C1-C4 alcohols in inert solvents diphenyl-methane, dibenzyl and diphenylacetylene along with active solvents benzophenone and diphenylsulfoxide have been measured. The values of gamma(i) in inert solvent decrease in the order: methanol > ethanol > n-propanol > n-butanol; n-propanol > isopropanol; n-butanol approximately isobutanol > tert-butanol > sec-butanol. but no regular order has been found in active solvent. The activity coefficients have been treated by Kretschmer-Wiebe association model combining with a Hildebrand-Scatchar d term. The self association constants K(A) of alcohols in inert solvent decrease in the order: methanol > ethanol > n-propanol > n-butanol; n-propanol > isopropanol; n-butanol > tert-butanol > isobutanol approximately sec-butanol. At the same temperature, the values of K(A) of each alcohol in the studied inert solvents are nearly equal. It can be safely assumed that each alcohol in the solvents which have two benzene rings are all having a common value K(A). In addition, using the average K(A) in studied inert solvents, the cross association constant K(AB) of alcohol with active solvent has been evaluated. The values of K(AB) decrease in the order: methanol > ethanol > n-propanol > n-butanol; n-propanol > isopropanol; n-butanol > isobutanol > sec-butanol > tert-butanol. It has been found that the associated ability of alcohol with diphenylsulfoxide is greater than with benzophenone. On condition that the factor K(AB) is comparable with K(A), the value of gamma(i) would be close to unity. And the irregular phenomenon of gamma(i) in active solvent can be given a satisfactory explanation." @default.
- W2898036501 created "2018-10-26" @default.
- W2898036501 creator A5026207988 @default.
- W2898036501 creator A5030542604 @default.
- W2898036501 creator A5060909233 @default.
- W2898036501 creator A5075884099 @default.
- W2898036501 creator A5082405211 @default.
- W2898036501 date "1992-01-01" @default.
- W2898036501 modified "2023-09-24" @default.
- W2898036501 title "THERMODYNAMIC STUDY OF ASSOCIATED SOLUTIONS OF ALCOHOLS IN AROMATICS BY GAS-LIQUID-CHROMATOGRAPHY" @default.
- W2898036501 hasPublicationYear "1992" @default.
- W2898036501 type Work @default.
- W2898036501 sameAs 2898036501 @default.
- W2898036501 citedByCount "0" @default.
- W2898036501 crossrefType "journal-article" @default.
- W2898036501 hasAuthorship W2898036501A5026207988 @default.
- W2898036501 hasAuthorship W2898036501A5030542604 @default.
- W2898036501 hasAuthorship W2898036501A5060909233 @default.
- W2898036501 hasAuthorship W2898036501A5075884099 @default.
- W2898036501 hasAuthorship W2898036501A5082405211 @default.
- W2898036501 hasConcept C170961132 @default.
- W2898036501 hasConcept C178790620 @default.
- W2898036501 hasConcept C184651966 @default.
- W2898036501 hasConcept C185592680 @default.
- W2898036501 hasConcept C2777271787 @default.
- W2898036501 hasConcept C2777691172 @default.
- W2898036501 hasConcept C2777713963 @default.
- W2898036501 hasConcept C2778292535 @default.
- W2898036501 hasConcept C2778893608 @default.
- W2898036501 hasConcept C2779607525 @default.
- W2898036501 hasConcept C2780021418 @default.
- W2898036501 hasConcept C2780161600 @default.
- W2898036501 hasConcept C2780471494 @default.
- W2898036501 hasConcept C2781066024 @default.
- W2898036501 hasConcept C2781213060 @default.
- W2898036501 hasConceptScore W2898036501C170961132 @default.
- W2898036501 hasConceptScore W2898036501C178790620 @default.
- W2898036501 hasConceptScore W2898036501C184651966 @default.
- W2898036501 hasConceptScore W2898036501C185592680 @default.
- W2898036501 hasConceptScore W2898036501C2777271787 @default.
- W2898036501 hasConceptScore W2898036501C2777691172 @default.
- W2898036501 hasConceptScore W2898036501C2777713963 @default.
- W2898036501 hasConceptScore W2898036501C2778292535 @default.
- W2898036501 hasConceptScore W2898036501C2778893608 @default.
- W2898036501 hasConceptScore W2898036501C2779607525 @default.
- W2898036501 hasConceptScore W2898036501C2780021418 @default.
- W2898036501 hasConceptScore W2898036501C2780161600 @default.
- W2898036501 hasConceptScore W2898036501C2780471494 @default.
- W2898036501 hasConceptScore W2898036501C2781066024 @default.
- W2898036501 hasConceptScore W2898036501C2781213060 @default.
- W2898036501 hasIssue "1" @default.
- W2898036501 hasLocation W28980365011 @default.
- W2898036501 hasOpenAccess W2898036501 @default.
- W2898036501 hasPrimaryLocation W28980365011 @default.
- W2898036501 hasRelatedWork W1846405238 @default.
- W2898036501 hasRelatedWork W1993165528 @default.
- W2898036501 hasRelatedWork W2002059769 @default.
- W2898036501 hasRelatedWork W2064388486 @default.
- W2898036501 hasRelatedWork W2073362013 @default.
- W2898036501 hasRelatedWork W2759125420 @default.
- W2898036501 hasRelatedWork W2761422073 @default.
- W2898036501 hasRelatedWork W2801597656 @default.
- W2898036501 hasRelatedWork W2909877706 @default.
- W2898036501 hasRelatedWork W2924499744 @default.
- W2898036501 hasRelatedWork W2963129935 @default.
- W2898036501 hasRelatedWork W2978493270 @default.
- W2898036501 hasRelatedWork W2982275740 @default.
- W2898036501 hasRelatedWork W2986314450 @default.
- W2898036501 hasRelatedWork W2988210399 @default.
- W2898036501 hasRelatedWork W2998657011 @default.
- W2898036501 hasRelatedWork W2999317335 @default.
- W2898036501 hasRelatedWork W3017499866 @default.
- W2898036501 hasRelatedWork W3111179507 @default.
- W2898036501 hasRelatedWork W3167871762 @default.
- W2898036501 hasVolume "50" @default.
- W2898036501 isParatext "false" @default.
- W2898036501 isRetracted "false" @default.
- W2898036501 magId "2898036501" @default.
- W2898036501 workType "article" @default.