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- W2898037917 abstract "The interplay between Mn ions and corrole ligands gives rise to complex scenarios regarding the metal centers’ electronic properties expressing a range of high oxidation states and spin configurations. The resulting potential of Mn–corroles for applications such as catalysts or fuel cells has recently been demonstrated. However, despite being crucial for their functionality, the electronic structure of Mn–corroles is often hardly accessible with traditional techniques and thus is still under debate, especially under interfacial conditions. Here, we unravel the electronic ground state of the prototypical Mn-5,10,15-tris(pentafluorophenyl)corrole complex through X-ray spectroscopic investigations of ultrapure thin films and quantum chemical analysis. The theory-based interpretation of Mn photoemission and absorption fine structure spectra (3s and 2p and L2,3-edge, respectively) evidence a Mn(III) oxidation state with an S = 2 high-spin configuration. By referencing density functional theory calculations with the experiments, we lay the basis for extending our approach to the characterization of complex interfaces." @default.
- W2898037917 created "2018-10-26" @default.
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- W2898037917 date "2018-10-17" @default.
- W2898037917 modified "2023-10-14" @default.
- W2898037917 title "Unraveling the Oxidation and Spin State of Mn–Corrole through X-ray Spectroscopy and Quantum Chemical Analysis" @default.
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- W2898037917 cites W1970127494 @default.
- W2898037917 cites W1973214628 @default.
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- W2898037917 cites W1976372957 @default.
- W2898037917 cites W1978273949 @default.
- W2898037917 cites W1979087321 @default.
- W2898037917 cites W1979877635 @default.
- W2898037917 cites W1981368803 @default.
- W2898037917 cites W1983545193 @default.
- W2898037917 cites W1988091937 @default.
- W2898037917 cites W1996477530 @default.
- W2898037917 cites W2001127597 @default.
- W2898037917 cites W2002514812 @default.
- W2898037917 cites W2003794360 @default.
- W2898037917 cites W2004124981 @default.
- W2898037917 cites W2004706090 @default.
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- W2898037917 doi "https://doi.org/10.1021/acs.jpclett.8b02525" @default.
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