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- W2898047937 abstract "A convenient imine clip-and-cleave concept has been developed for the selective hydroxylation of non-activated C−H bonds of aliphatic aldehydes. Reaction of aldehydes with N,N-diethyl-ethylenediamine leads to the corresponding imine that binds copper(I) ions as a bidentate donor ligand. After exposure of a solution of this complex to dioxygen followed by acidic cleavage of the product the corresponding β-hydroxylated aldehyde forms. This concept was successfully applied to the hydroxylation of trimethylacetaldehyde as well as adamantane and diamantane 1-carbaldehydes. More information can be found in the Full Paper by S. Schindler, A. A. Fokin, M. C. Holthausen et al. on page 15543. Graphics by Sebastian Hattig. A convenient imine clip-and-cleave concept has been developed for the selective hydroxylation of non-activated C−H bonds of aliphatic aldehydes. Reaction of aldehydes with N,N-diethyl-ethylenediamine leads to the corresponding imine that binds copper(I) ions as a bidentate donor ligand. After exposure of a solution of this complex to dioxygen followed by acidic cleavage of the product the corresponding β-hydroxylated aldehyde forms. This concept was successfully applied to the hydroxylation of trimethylacetaldehyde as well as adamantane and diamantane 1-carbaldehydes. More information can be found in the Full Paper by S. Schindler, A. A. Fokin, M. C. Holthausen et al. on page 15543. Graphics by Sebastian Hattig." @default.
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- W2898047937 date "2018-09-04" @default.
- W2898047937 modified "2023-10-01" @default.
- W2898047937 title "Front Cover: Aerobic Aliphatic Hydroxylation Reactions by Copper Complexes: A Simple Clip‐and‐Cleave Concept (Chem. Eur. J. 58/2018)" @default.
- W2898047937 doi "https://doi.org/10.1002/chem.201804293" @default.
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