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• W2898049026 abstract "Abstract While the TeCF 3 moiety features promising properties and potential in a range of applications, no direct synthetic method exists for its incorporation into aromatic scaffolds. This report features the first direct catalytic method for the formation of C(sp 2 )−TeCF 3 bonds. The method relies on a Pd/Xantphos catalytic system and allows for the trifluoromethyltellurolation of aryl iodides. Our computational and experimental mechanistic analyses shed light on the privileged activity of Xantphos in this transformation." @default.
• W2898049026 created "2018-10-26" @default.
• W2898049026 creator A5044612746 @default.
• W2898049026 creator A5047300640 @default.
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• W2898049026 date "2018-11-20" @default.
• W2898049026 modified "2023-09-27" @default.
• W2898049026 title "Chemoselective Pd‐Catalyzed C‐TeCF ₃ Coupling of Aryl Iodides" @default.
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• W2898049026 doi "https://doi.org/10.1002/anie.201810950" @default.
• W2898049026 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30346648" @default.
• W2898049026 hasPublicationYear "2018" @default.
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