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• W2898050419 endingPage "24618" @default.
• W2898050419 startingPage "24609" @default.
• W2898050419 abstract "In this article, we demonstrate the electrochemical activity of AVP2O7/C (A = Li, Li0.5Na0.5, and Na) prepared by a scalable and easy-to-adopt oxalic dihydrazide assisted solution combustion method for application in sodium-ion batteries (SIBs). A series of compounds thus prepared are found to possess a monoclinic structure consisting of a three-dimensional porous network and sufficient void volume to facilitate facile intercalation/deintercalation of sodium ions. However, among the corresponding composites obtained with Super P carbon, the lithium analog, viz., LiVP2O7/C, demonstrates better electrochemical performance than the rest of the compositions, viz., Li0.5Na0.5VP2O7/C and NaVP2O7/C, when explored as anode in SIBs. In other words, LiVP2O7/C anode exhibits a stable reversible capacity of 125 mA h g–1 at 1 C rate (115 mA g–1) up to 100 cycles. Further, at 1 C rate condition, an acceptable capacity of 90 mA h g–1 has been observed up to 1000 cycles with a Coulombic efficiency of 99%, which is noteworthy. The currently prepared LiVP2O7/C anode validates its suitability for high capacity, long cycle life, and versatile rate capability by way of displaying significant capacity values of 118, 97, 70, 58, 50, and 40 mA h g–1, under the influence of 2, 3, 5, 10, 20, and 40 C rate, respectively. The study reports for the first time about the possibility of exploiting LiVP2O7/C as a potential insertion anode for high-rate SIB applications." @default.
• W2898050419 created "2018-10-26" @default.
• W2898050419 creator A5000011490 @default.
• W2898050419 creator A5038455154 @default.
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• W2898050419 date "2018-10-12" @default.
• W2898050419 modified "2023-09-27" @default.
• W2898050419 title "Exploration of AVP₂O₇/C (A = Li, Li_0.5Na_0.5, and Na) for High-Rate Sodium-Ion Battery Applications" @default.
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• W2898050419 doi "https://doi.org/10.1021/acs.jpcc.8b09451" @default.
• W2898050419 hasPublicationYear "2018" @default.
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