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• W2898059106 endingPage "13952" @default.
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• W2898059106 abstract "The organic chelating and bridging ligands 9,10-phenanthrenedione-9-oxime (phenoxH) and 9,10-phenanthrenedione-9,10-dioxime (phendoxH2) were synthesized and subsequently employed for the first time in heterometallic 3 d/4 f-metal cluster chemistry. The general reaction between CuCl2·2H2O, LnCl3·6H2O, phenoxH, and NEt3 in a 1:2:2:4 molar ratio, in a solvent mixture comprising MeCN and MeOH, afforded brown crystals of a new family of [Cu3LnCl3(phenox)6(MeOH)3] clusters (Ln = Gd (1), Tb (2), Dy (3)) that possess an unprecedented [Cu3Ln(μ-NO)6]3+ propeller-like core. Complexes 1-3 are the first {Cu3Ln} clusters in which the outer CuII and the central LnIII atoms are solely bridged by diatomic oximato bridges. The {Cu-N-O-Ln} bridging units are very distorted with torsion angles spanning the range 35.5-48.9° and 25.2-55.6° in 1 and 2, respectively. As a result, complexes 1-3 are antiferromagnetically coupled, in agreement with previously reported magnetostructural criteria for oximato-bridged Cu/Ln complexes. The magnetic susceptibility data for all complexes were nicely fit to an isotropic spin Hamiltonian (for 1) or a Hamiltonian that accounts for the spin of the CuII atoms, the spin component of the LnIII, the spin-orbit coupling (λ), an axial ligand-field component around the LnIII atoms (Δ), and the Zeeman effect (for the anisotropic 2 and 3). The resulting fit parameters were J = -1.34 cm-1 and g = 2.10 (1), J = -1.42 cm-1, gCu = 2.10, and Δ = -26.3 cm-1 (2), and J = -1.70 cm-1, gCu = 2.05, and Δ = -38.1 cm-1 (3). The reported fitting procedure, implemented in the PHI program, is here used for the first time. Even if this method is only valid in high-symmetry Ln environments, when it is properly used allows a very simple and efficient method to obtain the exchange parameters. In light of the negative anisotropy, compounds 2 and 3 were found to exhibit frequency-dependent tails of out-of-phase signals in the presence of a small external dc field, characteristic of the slow magnetization relaxation of a single-molecule magnet. By using the Kramers-Kronig equations, the effective energy barriers ( Ueff) were derived and reported as Ueff = 10.1 and 5.4 cm-1 for 2 and 3, respectively." @default.
• W2898059106 created "2018-10-26" @default.
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• W2898059106 date "2018-10-17" @default.
• W2898059106 modified "2023-10-10" @default.
• W2898059106 title "Oximato-Based Ligands in 3<i>d</i>/4<i>f</i>-Metal Cluster Chemistry: A Family of {Cu₃Ln} Complexes with a “Propeller”-like Topology and Single-Molecule Magnetic Behavior" @default.
• W2898059106 cites W1964297616 @default.
• W2898059106 cites W1965134115 @default.
• W2898059106 cites W1966052223 @default.
• W2898059106 cites W1966346685 @default.
• W2898059106 cites W1969360633 @default.
• W2898059106 cites W1976162255 @default.
• W2898059106 cites W1979303409 @default.
• W2898059106 cites W1981810963 @default.
• W2898059106 cites W2002974333 @default.
• W2898059106 cites W2005358242 @default.
• W2898059106 cites W2007752931 @default.
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• W2898059106 cites W2045894490 @default.
• W2898059106 cites W2045930046 @default.
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• W2898059106 doi "https://doi.org/10.1021/acs.inorgchem.8b02495" @default.
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