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- W2898080946 abstract "Abstract Two new luminescent Zn(II) metal–organic frameworks of [Zn(H2BPTC)](H2O)2 (1) and [Zn4(H2BPTC)2(SO4)2][(CH3)2NH2]4(H2O)4 (2) were constructed using zinc salts and 3,3′,5,5′‑biphenyltetracarboxylic acid (H4BPTC) as building blocks. The resulted MOFs were characterized by IR spectroscopy, thermogravimetric analysis and single crystal X-ray crystallography, and they exhibit different structural topologies: 1 presents a three dimensional (4,4)-connected network with {42.84} topology, while 2 can be described as a (4,6)-connected network with (32.62.72)(34.42.64.75) topology. These differences show that counter-anions play an important role in modulating structural and luminescent properties. Both 1 and 2 possess strong luminescence in suspensions, which can be selectively quenched by some specific nitroaromatics, Fe3+ ion and acetone." @default.
- W2898080946 created "2018-10-26" @default.
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- W2898080946 date "2018-12-01" @default.
- W2898080946 modified "2023-10-12" @default.
- W2898080946 title "Two Zn(II)-based metal-organic frameworks for selective detection of nitroaromatic explosives and Fe3+ ion" @default.
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- W2898080946 doi "https://doi.org/10.1016/j.inoche.2018.10.015" @default.
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