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- W2898083629 abstract "We report herein an efficient catalytic epoxidation reaction for the synthesis of epoxyketone (tert-butyl ((S)-4-methyl-1-((R)-2-methyloxiran-2-yl)-1-oxopentan-2-yl)carbamate), which is an important synthetic intermediate of carfilzomib. A series of bioinspired manganese complexes bearing N4 ligands are carefully investigated in the epoxidation of enone precursor with H2O2 as oxidant in the presence of carboxylic acid (e.g., acetic acid)." @default.
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- W2898083629 date "2019-03-01" @default.
- W2898083629 modified "2023-10-17" @default.
- W2898083629 title "Bioinspired manganese complexes catalyzed epoxidation for the synthesis of the epoxyketone fragment of carfilzomib" @default.
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- W2898083629 doi "https://doi.org/10.1016/j.cclet.2018.10.023" @default.
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