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• W2898091910 endingPage "9024" @default.
• W2898091910 startingPage "9014" @default.
• W2898091910 abstract "The temperature ( T) dependences of the emissions from the tetra- n-butylammonium salts of [{Mo6X8}Y6]2- (X, Y = Cl, Br, and I) in optically transparent polyethylene glycol dimethacrylate matrixes were studied in the T range of 3-300 K. [{Mo6Cl8}Y6]2-, [{Mo6Br8}Y6]2-, and [{Mo6I8}I6]2- showed the T-dependent emission characteristics similar to those of other hexanuclear Mo(II), Re(III), and W(II) clusters reported previously, while [{Mo6I8}Br6]2- and [{Mo6I8}Cl6]2- exhibited the emission properties different from those of other [{Mo6X8}Y6]2- clusters. The photophysical behavior of these clusters was explained by the excited triplet state spin-sublevel ( Φn, n = 1-4) model irrespective of the nature of X and Y. The zero-magnetic-field splitting energies between the lowest energy (Φ1) and the higher energy spin sublevels (Φ4 or Φ3) caused by the first- or second-order spin-orbit coupling, Δ E14 or Δ E13, were evaluated to be 620-870 or 50-99 cm-1, respectively. We found the linear correlation between the Δ E14 or Δ E13 value and the fourth power of the atomic number ( Z) of the inner halide X: Δ E14 or Δ E13 vs { Z(X)}4 (correlation coefficient: cc = ∼ 0.999). Furthermore, we also found the correlation between Δ E14 or Δ E13 and the 95Mo NMR chemical shift of the cluster. These findings gave very important insight into the spin-orbit coupling and zero-magnetic-field splitting in the excited triplet states of transition metal complexes." @default.
• W2898091910 created "2018-11-02" @default.
• W2898091910 creator A5003733957 @default.
• W2898091910 creator A5009382897 @default.
• W2898091910 creator A5047537389 @default.
• W2898091910 date "2018-10-26" @default.
• W2898091910 modified "2023-10-02" @default.
• W2898091910 title "Zero-Magnetic-Field Splitting in the Excited Triplet States of Octahedral Hexanuclear Molybdenum(II) Clusters: [{Mo₆X₈}Y₆]^2– (X, Y = Cl, Br, I)" @default.
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• W2898091910 doi "https://doi.org/10.1021/acs.jpca.8b09339" @default.
• W2898091910 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30365893" @default.
• W2898091910 hasPublicationYear "2018" @default.
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