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• W2898092004 abstract "A chemo-enzymatic pathway involving a Candida antarctica type B lipase was developed to produce (S)-γ-hydroxymethyl-α,β-butenolide methacrylate (HBO-m) and (S)-γ-hydroxymethyl-γ-butyrolactone methacrylate (2H-HBO-m) from (S)-γ-hydroxymethyl-γ-butyrolactone (HBO), a biobased molecule obtained from cellulose-derived levoglucosenone. The acrylated monomer was then copolymerized through a free radical process with methacrylamide and methylene-γ-valerolactone, a green intermediate. Finally, methylene-tetrahydropyranyl (S)-γ-hydroxymethyl-γ-butyrolactone (M-THP-2H-HBO), synthesized via α-methylenation of 2H-HBO, was copolymerized with methyl methacrylate to access copolyacrylates exhibiting high glass transition temperatures." @default.
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• W2898092004 date "2018-10-25" @default.
• W2898092004 modified "2023-09-30" @default.
• W2898092004 title "Chemo-Enzymatic Synthesis and Free Radical Polymerization of Renewable Acrylate Monomers from Cellulose-Based Lactones" @default.
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• W2898092004 doi "https://doi.org/10.1021/acssuschemeng.8b04707" @default.
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