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• W2898103227 abstract "An accurate mass transfer model is required to calculate the diffusion coefficient in polymers to describe the mass transfer of volatiles in process intensification, especially in the devolatilization units. However, the diffusion coefficient actually is variate rather than a fixed value due to the changing concentration and viscosity of polymer in the process of devolatilization. In this work, removal rates of the volatiles in liquid film were obtained by the intelligent gravity analysis, and a discrete mathematical model was established to compute the instantaneous dynamic diffusion coefficients. On the basis of a large number of experimental data, a correlation of diffusion coefficients was developed by dimensionless regression analysis with temperature, concentration, viscosity, molar mass, molecular polarity, etc. It can well describe the diffusion process in polymers. Furthermore, a molecular simulation was conducted to explore the proper means of the bonding method and force field in the calculatio..." @default.
• W2898103227 created "2018-11-02" @default.
• W2898103227 creator A5018846686 @default.
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• W2898103227 date "2018-10-24" @default.
• W2898103227 modified "2023-10-18" @default.
• W2898103227 title "Dynamic Analysis Model for the Diffusion Coefficient in High-Viscosity Polymer Solution" @default.
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• W2898103227 doi "https://doi.org/10.1021/acs.iecr.8b03966" @default.
• W2898103227 hasPublicationYear "2018" @default.
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