FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898157816> ?p ?o ?g. }

• W2898157816 endingPage "7033" @default.
• W2898157816 startingPage "7029" @default.
• W2898157816 abstract "A novel cationic silicon–sulfur Lewis pair with a chiral H8-binaphthyl backbone is reported. It catalyzes otherwise sluggish Diels–Alder reactions of cyclohexa-1,3-diene and chalcone derivatives in good yields and decent enantioselectivities (up to 81% ee). The enantioinduction is highest with a [1,1′-biphenyl]-4-yl substituent at the carbonyl carbon atom. This moiety can be later converted into a carboxyl group by Baeyer–Villiger oxidation. The same oxidant also epoxidizes the double bond in the cycloadduct, and the epoxide engages in a lactonization with the carboxylic acid. Synthetically interesting hexahydro-3,6-methanobenzofuran-2(3H)-one skeletons are obtained in one pot." @default.
• W2898157816 created "2018-11-02" @default.
• W2898157816 creator A5002792140 @default.
• W2898157816 creator A5010232927 @default.
• W2898157816 date "2018-10-26" @default.
• W2898157816 modified "2023-09-30" @default.
• W2898157816 title "Achieving Enantioselectivity in Difficult Cyclohexa-1,3-diene Diels–Alder Reactions with Sulfur-Stabilized Silicon Cations as Lewis Acid Catalysts" @default.
• W2898157816 cites W1930186090 @default.
• W2898157816 cites W1964531074 @default.
• W2898157816 cites W1965170231 @default.
• W2898157816 cites W1976513692 @default.
• W2898157816 cites W1985652286 @default.
• W2898157816 cites W2003362809 @default.
• W2898157816 cites W2006185667 @default.
• W2898157816 cites W2020220720 @default.
• W2898157816 cites W2032872060 @default.
• W2898157816 cites W2051048532 @default.
• W2898157816 cites W2051293921 @default.
• W2898157816 cites W2064606955 @default.
• W2898157816 cites W2070002819 @default.
• W2898157816 cites W2073327897 @default.
• W2898157816 cites W2076099511 @default.
• W2898157816 cites W2083828797 @default.
• W2898157816 cites W2096732108 @default.
• W2898157816 cites W2109075829 @default.
• W2898157816 cites W2291377880 @default.
• W2898157816 cites W2295837975 @default.
• W2898157816 cites W2330235107 @default.
• W2898157816 cites W2335705928 @default.
• W2898157816 cites W2507803932 @default.
• W2898157816 cites W2508865864 @default.
• W2898157816 cites W2563319670 @default.
• W2898157816 cites W2791516888 @default.
• W2898157816 cites W2952622785 @default.
• W2898157816 cites W2952744427 @default.
• W2898157816 cites W2952827612 @default.
• W2898157816 doi "https://doi.org/10.1021/acs.orglett.8b02945" @default.
• W2898157816 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30362776" @default.
• W2898157816 hasPublicationYear "2018" @default.
• W2898157816 type Work @default.
• W2898157816 sameAs 2898157816 @default.
• W2898157816 citedByCount "14" @default.
• W2898157816 countsByYear W28981578162019 @default.
• W2898157816 countsByYear W28981578162020 @default.
• W2898157816 countsByYear W28981578162021 @default.
• W2898157816 countsByYear W28981578162022 @default.
• W2898157816 countsByYear W28981578162023 @default.
• W2898157816 crossrefType "journal-article" @default.
• W2898157816 hasAuthorship W2898157816A5002792140 @default.
• W2898157816 hasAuthorship W2898157816A5010232927 @default.
• W2898157816 hasConcept C155647269 @default.
• W2898157816 hasConcept C161790260 @default.
• W2898157816 hasConcept C163638829 @default.
• W2898157816 hasConcept C176933379 @default.
• W2898157816 hasConcept C178790620 @default.
• W2898157816 hasConcept C183882617 @default.
• W2898157816 hasConcept C185592680 @default.
• W2898157816 hasConcept C2776568683 @default.
• W2898157816 hasConcept C2776920199 @default.
• W2898157816 hasConcept C2778689049 @default.
• W2898157816 hasConcept C2778733088 @default.
• W2898157816 hasConcept C2779940776 @default.
• W2898157816 hasConcept C2780764945 @default.
• W2898157816 hasConcept C518881349 @default.
• W2898157816 hasConcept C68381374 @default.
• W2898157816 hasConcept C71240020 @default.
• W2898157816 hasConceptScore W2898157816C155647269 @default.
• W2898157816 hasConceptScore W2898157816C161790260 @default.
• W2898157816 hasConceptScore W2898157816C163638829 @default.
• W2898157816 hasConceptScore W2898157816C176933379 @default.
• W2898157816 hasConceptScore W2898157816C178790620 @default.
• W2898157816 hasConceptScore W2898157816C183882617 @default.
• W2898157816 hasConceptScore W2898157816C185592680 @default.
• W2898157816 hasConceptScore W2898157816C2776568683 @default.
• W2898157816 hasConceptScore W2898157816C2776920199 @default.
• W2898157816 hasConceptScore W2898157816C2778689049 @default.
• W2898157816 hasConceptScore W2898157816C2778733088 @default.
• W2898157816 hasConceptScore W2898157816C2779940776 @default.
• W2898157816 hasConceptScore W2898157816C2780764945 @default.
• W2898157816 hasConceptScore W2898157816C518881349 @default.
• W2898157816 hasConceptScore W2898157816C68381374 @default.
• W2898157816 hasConceptScore W2898157816C71240020 @default.
• W2898157816 hasFunder F4320320879 @default.
• W2898157816 hasFunder F4320323688 @default.
• W2898157816 hasIssue "22" @default.
• W2898157816 hasLocation W28981578161 @default.
• W2898157816 hasLocation W28981578162 @default.
• W2898157816 hasOpenAccess W2898157816 @default.
• W2898157816 hasPrimaryLocation W28981578161 @default.
• W2898157816 hasRelatedWork W2001046702 @default.
• W2898157816 hasRelatedWork W2079006159 @default.
• W2898157816 hasRelatedWork W2105586224 @default.
• W2898157816 hasRelatedWork W2128093567 @default.
• W2898157816 hasRelatedWork W2134085470 @default.
• W2898157816 hasRelatedWork W2517799130 @default.
• W2898157816 hasRelatedWork W2535705715 @default.
• W2898157816 hasRelatedWork W2896753382 @default.
• W2898157816 hasRelatedWork W2951126009 @default.

• next