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• W2898171837 endingPage "25514" @default.
• W2898171837 startingPage "25506" @default.
• W2898171837 abstract "The dynamic motion, within the lattice of single crystal CH3NH3PbBr3 (001) hybrid halide perovskite, was investigated using powder and single crystal X-ray diffraction, and X-ray photoemission spectroscopy. Single crystal X-ray diffraction studies indicate the methylammonium cation adopts multiple orientations within the crystal, at room temperature, evidence of a disordered methylammonium sublattice within a rigid and ordered PbBr3 matrix lattice. From the Br 3d5/2 core level photoemission temperature dependence, an effective Debye temperature of 160 ± 22 K can be estimated, while the Pb 4f7/2 core-level Debye–Waller factor plots suggest an effective Debye temperature of 202 ± 131 K, indicative of a very rigid lattice along the (001) direction. The combination of X-ray diffraction with temperature dependent X-ray photoemission spectroscopy for bromine and lead core level peaks supports the characterization of CH3NH3PbBr3 as a lattice polar liquid crystal, as CH3NH3PbBr3 does not meet the criteria require..." @default.
• W2898171837 created "2018-11-02" @default.
• W2898171837 creator A5000832386 @default.
• W2898171837 creator A5015619826 @default.
• W2898171837 creator A5021621003 @default.
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• W2898171837 creator A5040624271 @default.
• W2898171837 creator A5041167652 @default.
• W2898171837 creator A5081897981 @default.
• W2898171837 creator A5090134133 @default.
• W2898171837 date "2018-10-23" @default.
• W2898171837 modified "2023-09-26" @default.
• W2898171837 title "Rotationally Free and Rigid Sublattices of the Single Crystal Perovskite CH₃NH₃PbBr₃ (001): The Case of the Lattice Polar Liquid" @default.
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