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• W2898179629 abstract "A radical-triggered tandem cyclization of 1,6-enynes has been developed herein. Strained 1H-cyclopropa[b]naphthalene-2,7-diones are successfully obtained in moderate to good yields with excellent stereoselectivity. Mechanistic studies reveal a key role of water in generating a hydroxyl radical that initiates a sequential Michael addition/ring closure pathway. Importantly, the formed hydroxyl is proposed to be a good leaving group during the cyclopropane ring formation." @default.
• W2898179629 created "2018-11-02" @default.
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• W2898179629 date "2018-10-25" @default.
• W2898179629 modified "2023-10-15" @default.
• W2898179629 title "Radical-Triggered Tandem Cyclization of 1,6-Enynes with H₂O: A Way to Access Strained 1<i>H</i>-Cyclopropa[<i>b</i>]naph thalene-2,7-diones" @default.
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• W2898179629 doi "https://doi.org/10.1021/acs.orglett.8b03007" @default.
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