Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898386475> ?p ?o ?g. }
- W2898386475 endingPage "201" @default.
- W2898386475 startingPage "193" @default.
- W2898386475 abstract "An extensive literature review of the mechanistic modeling of n-heptane and cyclohexane pyrolysis was carried out. It was shown that Rice–Kossiakoff free radical theory does not adequately account for product distributions of n-heptane pyrolysis in the high conversion regime. Secondary reactions of alpha higher olefins and di-olefins accounted for the major products (ethene, propene and 1-butene) of n-heptane pyrolysis. Predicted product distributions (CH4, C2H4, C3H6, 1-C4H8 and 1,3-C4H6) of n-heptane pyrolysis showed very good agreement with experimental data. The product distributions of cyclohexane pyrolysis in the high conversion regime were rationalized and adequately accounted for using decomposition reactions of cyclohexyl bi-radicals followed by secondary reactions of major primary products such as C3H6 and 1,3-C4H6. The latter expanded mechanism can be used to model cyclohexane pyrolysis in the high conversion regime. Rate parameters (pre-exponential factors and activation energy) for each of the elementary reactions of n-heptane mechanistic model were either obtained from the literature or estimated using thermochemical parameters. The use of steady state approximation in mathematical modeling of n-heptane pyrolysis led to erroneous results." @default.
- W2898386475 created "2018-11-02" @default.
- W2898386475 creator A5086902244 @default.
- W2898386475 creator A5088734399 @default.
- W2898386475 date "2018-10-25" @default.
- W2898386475 modified "2023-09-25" @default.
- W2898386475 title "A review of mechanistic and mathematical modeling of n-heptane and cyclohexane pyrolysis" @default.
- W2898386475 cites W106758141 @default.
- W2898386475 cites W1963879576 @default.
- W2898386475 cites W1965547957 @default.
- W2898386475 cites W1970994283 @default.
- W2898386475 cites W1972043262 @default.
- W2898386475 cites W1973725507 @default.
- W2898386475 cites W1973867777 @default.
- W2898386475 cites W1975949356 @default.
- W2898386475 cites W1983322951 @default.
- W2898386475 cites W1987120783 @default.
- W2898386475 cites W1991293272 @default.
- W2898386475 cites W1992393986 @default.
- W2898386475 cites W1993381050 @default.
- W2898386475 cites W1995187232 @default.
- W2898386475 cites W1995566916 @default.
- W2898386475 cites W1996197239 @default.
- W2898386475 cites W1997094728 @default.
- W2898386475 cites W2000212437 @default.
- W2898386475 cites W2003828762 @default.
- W2898386475 cites W2006855907 @default.
- W2898386475 cites W2009917258 @default.
- W2898386475 cites W2025762817 @default.
- W2898386475 cites W2026244427 @default.
- W2898386475 cites W2026907432 @default.
- W2898386475 cites W2029704760 @default.
- W2898386475 cites W2033617642 @default.
- W2898386475 cites W2040086139 @default.
- W2898386475 cites W2041218731 @default.
- W2898386475 cites W2041901933 @default.
- W2898386475 cites W2042818909 @default.
- W2898386475 cites W2045882689 @default.
- W2898386475 cites W2049605144 @default.
- W2898386475 cites W2061013442 @default.
- W2898386475 cites W2061746608 @default.
- W2898386475 cites W2064209702 @default.
- W2898386475 cites W2070309182 @default.
- W2898386475 cites W2075704424 @default.
- W2898386475 cites W2075732024 @default.
- W2898386475 cites W2078109086 @default.
- W2898386475 cites W2086489813 @default.
- W2898386475 cites W2091831673 @default.
- W2898386475 cites W2099361599 @default.
- W2898386475 cites W2106481523 @default.
- W2898386475 cites W2122465464 @default.
- W2898386475 cites W2145498735 @default.
- W2898386475 cites W2148041209 @default.
- W2898386475 cites W2155155530 @default.
- W2898386475 cites W2157748050 @default.
- W2898386475 cites W2168260521 @default.
- W2898386475 cites W2240021929 @default.
- W2898386475 cites W2318164033 @default.
- W2898386475 cites W2321204898 @default.
- W2898386475 cites W2485403932 @default.
- W2898386475 cites W2585391496 @default.
- W2898386475 cites W2950124773 @default.
- W2898386475 cites W2952233492 @default.
- W2898386475 cites W905957477 @default.
- W2898386475 doi "https://doi.org/10.1007/s13203-018-0213-x" @default.
- W2898386475 hasPublicationYear "2018" @default.
- W2898386475 type Work @default.
- W2898386475 sameAs 2898386475 @default.
- W2898386475 citedByCount "4" @default.
- W2898386475 countsByYear W28983864752020 @default.
- W2898386475 countsByYear W28983864752021 @default.
- W2898386475 countsByYear W28983864752022 @default.
- W2898386475 countsByYear W28983864752023 @default.
- W2898386475 crossrefType "journal-article" @default.
- W2898386475 hasAuthorship W2898386475A5086902244 @default.
- W2898386475 hasAuthorship W2898386475A5088734399 @default.
- W2898386475 hasBestOaLocation W28983864751 @default.
- W2898386475 hasConcept C147597530 @default.
- W2898386475 hasConcept C161790260 @default.
- W2898386475 hasConcept C178790620 @default.
- W2898386475 hasConcept C180238147 @default.
- W2898386475 hasConcept C185592680 @default.
- W2898386475 hasConcept C2777854178 @default.
- W2898386475 hasConcept C2778237882 @default.
- W2898386475 hasConcept C36759035 @default.
- W2898386475 hasConceptScore W2898386475C147597530 @default.
- W2898386475 hasConceptScore W2898386475C161790260 @default.
- W2898386475 hasConceptScore W2898386475C178790620 @default.
- W2898386475 hasConceptScore W2898386475C180238147 @default.
- W2898386475 hasConceptScore W2898386475C185592680 @default.
- W2898386475 hasConceptScore W2898386475C2777854178 @default.
- W2898386475 hasConceptScore W2898386475C2778237882 @default.
- W2898386475 hasConceptScore W2898386475C36759035 @default.
- W2898386475 hasIssue "4" @default.
- W2898386475 hasLocation W28983864751 @default.
- W2898386475 hasOpenAccess W2898386475 @default.
- W2898386475 hasPrimaryLocation W28983864751 @default.
- W2898386475 hasRelatedWork W1546908342 @default.