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• W2898480982 abstract "In the present study, dual-functional CuO–Fe3O4 magnetic nanocomposites (MNCs) have been prepared through a simple impregnation method and used as catalyst for photocatalytic oxidative desulfurization of model-fuel (dibenzothiophene, DBT in n-hexane) and real naphtha at moderate conditions. The CuO–Fe3O4 MNCs were characterized by X-ray diffraction, BET surface area and pore volume using nitrogen adsorption–desorption and VSM methods The effects of different reaction parameters such as initial DBT concentration in model-fuel, CuO–Fe3O4 MNCs dose, reaction time, H2O2/DBT molar ratio and CuO:Fe3O4 weight ratio of the MNCs were studied in detail. Results for model-fuel treatment showed that the prepared nanocomposite can eliminate 95.2% of DBT after 120 min under the following conditions: CuO:Fe3O4 weight ratio of 1:1, catalyst dose of 10 g/l, H2O2/DBT mole ratio of 7.5:1 and initial DBT concentration of 250 mg/l. Furthermore, 93% of sulfur conversion was obtained for naphtha fuel (initial sulfur concentration of 533 mg/l) after 240 min reaction time. The synthesized CuO–Fe3O4 magnetic nanocomposites combines the photocatalytic activity of CuO and the adsorption capacity of both Fe3O4 and CuO species, which make it have important applications in the deep desulfurization of liquid fuels." @default.
• W2898480982 created "2018-11-02" @default.
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• W2898480982 date "2018-12-01" @default.
• W2898480982 modified "2023-10-18" @default.
• W2898480982 title "Photocatalytic oxidative desulfurization of liquid petroleum fuels using magnetic CuO–Fe3O4 nanocomposites" @default.
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• W2898480982 doi "https://doi.org/10.1016/j.jece.2018.10.031" @default.
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