Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898483468> ?p ?o ?g. }
- W2898483468 endingPage "102729" @default.
- W2898483468 startingPage "102729" @default.
- W2898483468 abstract "Abstract Here we report a versatile strategy based on the use of BaO as an electron promoter to boost the photocatalytic activity of TiO2 based, Pd supported photocatalysts for hydrogen production from water splitting. Pd-BaO nanoparticles were deposited on the TiO2 surface by simple chemical reduction method using NaBH4 as reductant. The as-synthesized Pd-BaO/TiO2 photocatalysts showed a remarkably high performance in hydrogen production, approximately 29.6 mmol g−1h−1 using an ethanol-water mixture (5% ethanol and 95% water), which is two times higher than Pd/TiO2 photocatalyst, where the latter is already regarded as the most active metal based TiO2 photocatalysts for H2 production. This high hydrogen production efficiency was attributed to the inherent high catalytic activity of palladium nanoparticles and electronic promotional effect of BaO. The Ba (in the form of BaO) greatly enhanced the electron transfer from the semiconductor conduction band to Pd centers by raising the Fermi level of TiO2 during photo-irradiation. Most importantly, Pd is present exclusively in zero oxidation state, which is ideal for proton reduction in the as-prepared photocatalysts due to close proximity of highly electropositive BaO. The structural morphologies and mechanistic aspects of the Pd-BaO/TiO2 photocatalysts are addressed by using UV–Vis/DRS, XRD, TEM, and XPS characterization techniques." @default.
- W2898483468 created "2018-11-02" @default.
- W2898483468 creator A5011291997 @default.
- W2898483468 creator A5020512076 @default.
- W2898483468 creator A5024081780 @default.
- W2898483468 creator A5040540556 @default.
- W2898483468 creator A5042349586 @default.
- W2898483468 creator A5047798078 @default.
- W2898483468 creator A5052175483 @default.
- W2898483468 creator A5058675280 @default.
- W2898483468 date "2019-02-01" @default.
- W2898483468 modified "2023-10-17" @default.
- W2898483468 title "Remarkable effect of BaO on photocatalytic H2 evolution from water splitting via TiO2 (P25) supported palladium nanoparticles" @default.
- W2898483468 cites W1832514381 @default.
- W2898483468 cites W1839265271 @default.
- W2898483468 cites W1965296958 @default.
- W2898483468 cites W1965932088 @default.
- W2898483468 cites W1966238717 @default.
- W2898483468 cites W1977632195 @default.
- W2898483468 cites W1979112470 @default.
- W2898483468 cites W1983436405 @default.
- W2898483468 cites W1985776665 @default.
- W2898483468 cites W1987000520 @default.
- W2898483468 cites W1990007852 @default.
- W2898483468 cites W1992277893 @default.
- W2898483468 cites W1993943081 @default.
- W2898483468 cites W1995811515 @default.
- W2898483468 cites W2004168114 @default.
- W2898483468 cites W2009752516 @default.
- W2898483468 cites W2025300800 @default.
- W2898483468 cites W2025900374 @default.
- W2898483468 cites W2029216783 @default.
- W2898483468 cites W2029521163 @default.
- W2898483468 cites W2031211436 @default.
- W2898483468 cites W2036804350 @default.
- W2898483468 cites W2038792689 @default.
- W2898483468 cites W2039306727 @default.
- W2898483468 cites W2039395090 @default.
- W2898483468 cites W2039440317 @default.
- W2898483468 cites W2039475059 @default.
- W2898483468 cites W2041396206 @default.
- W2898483468 cites W2045139339 @default.
- W2898483468 cites W2046849735 @default.
- W2898483468 cites W2052264804 @default.
- W2898483468 cites W2065750769 @default.
- W2898483468 cites W2066078143 @default.
- W2898483468 cites W2069329795 @default.
- W2898483468 cites W2071706572 @default.
- W2898483468 cites W2072350939 @default.
- W2898483468 cites W2073856340 @default.
- W2898483468 cites W2074623730 @default.
- W2898483468 cites W2085086110 @default.
- W2898483468 cites W2093100223 @default.
- W2898483468 cites W2107874807 @default.
- W2898483468 cites W2115556754 @default.
- W2898483468 cites W2131983491 @default.
- W2898483468 cites W2141597032 @default.
- W2898483468 cites W2162931499 @default.
- W2898483468 cites W2163287450 @default.
- W2898483468 cites W2167490277 @default.
- W2898483468 cites W2216126353 @default.
- W2898483468 cites W2412451595 @default.
- W2898483468 cites W2468046551 @default.
- W2898483468 cites W2505054064 @default.
- W2898483468 cites W2578038424 @default.
- W2898483468 cites W2578279687 @default.
- W2898483468 cites W2593481485 @default.
- W2898483468 cites W2601004027 @default.
- W2898483468 cites W2785856033 @default.
- W2898483468 cites W2802398876 @default.
- W2898483468 cites W771522245 @default.
- W2898483468 doi "https://doi.org/10.1016/j.jece.2018.10.044" @default.
- W2898483468 hasPublicationYear "2019" @default.
- W2898483468 type Work @default.
- W2898483468 sameAs 2898483468 @default.
- W2898483468 citedByCount "28" @default.
- W2898483468 countsByYear W28984834682019 @default.
- W2898483468 countsByYear W28984834682020 @default.
- W2898483468 countsByYear W28984834682021 @default.
- W2898483468 countsByYear W28984834682022 @default.
- W2898483468 countsByYear W28984834682023 @default.
- W2898483468 crossrefType "journal-article" @default.
- W2898483468 hasAuthorship W2898483468A5011291997 @default.
- W2898483468 hasAuthorship W2898483468A5020512076 @default.
- W2898483468 hasAuthorship W2898483468A5024081780 @default.
- W2898483468 hasAuthorship W2898483468A5040540556 @default.
- W2898483468 hasAuthorship W2898483468A5042349586 @default.
- W2898483468 hasAuthorship W2898483468A5047798078 @default.
- W2898483468 hasAuthorship W2898483468A5052175483 @default.
- W2898483468 hasAuthorship W2898483468A5058675280 @default.
- W2898483468 hasConcept C127413603 @default.
- W2898483468 hasConcept C155672457 @default.
- W2898483468 hasConcept C161790260 @default.
- W2898483468 hasConcept C171250308 @default.
- W2898483468 hasConcept C178790620 @default.
- W2898483468 hasConcept C179104552 @default.
- W2898483468 hasConcept C185592680 @default.
- W2898483468 hasConcept C192562407 @default.