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- W2898508738 abstract "A general access to the spiroimine skeleton of gymnodimine and spirolides is described, relying on the construction of the cyclohexene fragment using an enantiocontrolled Diels–Alder reaction, the installation of the all-carbon quaternary stereocenter through a stereocontrolled alkylation or aldolisation and the elaboration of the lateral chains at C7 and C22 using Wittig–Horner olefinations. The spiroimine core of gymnodimine is made available through a 16-step linear sequence in a 21 % overall yield." @default.
- W2898508738 created "2018-11-02" @default.
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- W2898508738 date "2019-01-02" @default.
- W2898508738 modified "2023-09-26" @default.
- W2898508738 title "An Approach towards the Synthesis of the Spiroimine Fragment of 13-Desmethylspirolide C and Gymnodimine A" @default.
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- W2898508738 doi "https://doi.org/10.1002/chem.201804972" @default.
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