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- W2898571587 abstract "Abstract The exploration of cost‐effective yet high‐efficiency inexpensive electrocatalysts for the hydrogen evolution reaction (HER) is of critical significance for future renewable energy conversion technologies. A feasible electrospinning strategy to construct a novel 1D hierarchical nanoarchitecture comprising Ni 3 Fe nanoalloy‐encapsulated carbon nanotubes grown onto N‐doped carbon nanofibers (abbreviated as Ni 3 Fe@N‐C NT/NFs) is demonstrated here. Benefiting from the abundant firmly immobilized Ni 3 Fe nanoparticles for catalytic sites and hierarchical fibrous nanostructures for effective electron transport and mass diffusion, the resultant Ni 3 Fe@N‐C NT/NFs display an extraordinary HER activity with a low overpotential of 72 mV to reach a current density of 10 mA cm −2 in KOH medium and a remarkable stability for 40 000 s. Theoretical studies corroborate that the resultant Ni 3 Fe@N‐C NT/NFs exhibit a favorable Gibbs free energy of hydrogen adsorption (Δ G H* = −0.14 eV), further manifesting their superior HER activity. The present work will advance the development of highly efficient nonprecious electrocatalysts for energy conversion." @default.
- W2898571587 created "2018-11-02" @default.
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- W2898571587 date "2018-10-25" @default.
- W2898571587 modified "2023-10-17" @default.
- W2898571587 title "Encapsulation of Ni<sub>3</sub>Fe Nanoparticles in N‐Doped Carbon Nanotube–Grafted Carbon Nanofibers as High‐Efficiency Hydrogen Evolution Electrocatalysts" @default.
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- W2898571587 doi "https://doi.org/10.1002/adfm.201805828" @default.
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