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• W2898643849 endingPage "1783" @default.
• W2898643849 startingPage "1779" @default.
• W2898643849 abstract "Abstract Elemental white phosphorus (P 4 ) is well recognized as a critical precursor to organophosphorus compounds. However, regulatory constraints stemming from the toxic and pyrophoric nature of white phosphorus have significantly limited its accessibility. Herein is described a new approach to white phosphorus storage and release based on a unique example of photolytic reductive elimination of the tetrahedral P 4 molecule from a mononuclear cyclo‐P 4 molybdenum complex. The latter functions as an air‐stable, chemically‐deactivated source of white phosphorus. The system features efficient photo‐release of white phosphorus using inexpensive violet LED sources. Additionally, high‐yield recapture of unspent white phosphorus by the molybdenum center can be achieved by post‐photolysis heating at convenient temperatures." @default.
• W2898643849 created "2018-11-09" @default.
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• W2898643849 date "2018-11-14" @default.
• W2898643849 modified "2023-10-16" @default.
• W2898643849 title "Photolytic Reductive Elimination of White Phosphorus from a Mononuclear <i>cyclo</i> ‐P ₄ Transition Metal Complex" @default.
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• W2898643849 doi "https://doi.org/10.1002/anie.201809042" @default.
• W2898643849 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30370975" @default.
• W2898643849 hasPublicationYear "2018" @default.
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