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- W2898760592 abstract "The high price of fuel cells is mainly attributed to the low catalytic efficiency and short working life of the state-of-the-art commercial catalysts for the oxygen reduction reaction. Hereon, a nitrogen-doped mesoporous carbon (NMC) with a roelike shape have been synthesized as the carbon support for the platinum (Pt) catalyst, which has a high specific surface area and pore volume. The doping with nitrogen creates many active sites on the NMC, which can enhance the catalytic activity of the supported Pt nanoparticles. The synthesis of the NMC is simple and reproducible, which uses polydopamine as the precursor and can be conveniently accomplished at room temperature. The Pt nanoparticles loaded on the NMC (Pt/NMC) exhibit a high mass activity (0.9 V vs reversible hydrogen electrode) of 0.384 A mgPt–1 in acidic media, which is 8.1 times of the catalyst using Vulcan XC-72R as the support (Pt/Vulcan) and prepared by the same synthetic process, and 5.9 times of the commercialized catalyst (Pt/C-com, 20 wt %). The Pt/NMC also exhibits a better electrochemical stability. Compared to the severe degradation of the Pt/Vulcan and the Pt/C-com after the accelerated durability test (5000 cycles), the Pt/NMC remained high catalytic activity and electrochemical active surface area, which may be due to the suitable morphology and the influence of nitrogen in the NMC." @default.
- W2898760592 created "2018-11-09" @default.
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- W2898760592 date "2018-11-01" @default.
- W2898760592 modified "2023-10-15" @default.
- W2898760592 title "Platinum Nanoparticles Dispersed on High-Surface-Area Roelike Nitrogen-Doped Mesoporous Carbon for Oxygen Reduction Reaction" @default.
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- W2898760592 doi "https://doi.org/10.1021/acsaem.8b01242" @default.
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