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- W2898837746 abstract "以2,6-吡啶二甲酸为原料,经酰化、酯化、胺解、亲和加成合成2,6-吡啶二甲酰肼-2-羟基萘甲酰腙(L1).用紫外-可见吸收光谱、荧光光谱、荧光寿命方法研究了酸碱对L1互变异构的影响及L1、Cu(Ⅱ)、铜运输蛋白(copper trafficking protein,apoCopC)三者的相互结合.结果表明,在pH=7.4、50 mmol·L-1 Tris-HCl缓冲条件下,L1可分别与Cu(Ⅱ) 、apoCopC结合形成1∶1的配合物,条件结合常数分别为3.32× 106 mol-1·L和4.01×105 mol-1·L;而Cu(Ⅱ)-L1与apoCopC结合形成1∶1复合物的条件结合常数为8.09×105 mol-1·L.荧光共振能量转移、分子对接模拟表明,L1结合在apoCopC的N端,光谱滴定证实L1、Cu(Ⅱ)、apoCopC可形成以Cu(Ⅱ)为中心的三元配合物." @default.
- W2898837746 created "2018-11-09" @default.
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- W2898837746 date "2015-01-01" @default.
- W2898837746 modified "2023-10-12" @default.
- W2898837746 title "Spectral Studies on Complex of 2,6-Pyridine Diformylhydrazine 2-Hydroxylnaphthene Carboxylic Hydrazone-Cu(II)-CopC" @default.
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