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- W2898857922 abstract "We report the formation of an icosahedral quasicrystal and its approximant in the Ga–Pd–Sc alloy. The primitive-type quasicrystal with a six-dimensional lattice constant of 0.713 nm formed in the melt-quenched Ga53Pd30Sc17 alloy, with a similar composition to that of the Ga55Pd30Sc15 1/1 approximant. The atomic-scale observation and chemical analysis of the 1/1 approximant by scanning transmission electron microscopy and energy-dispersive X-ray spectroscopy showed that the approximant consisted of Tsai-type clusters with a characteristic chemical ordering. Furthermore, a series of approximants were observed in the Ga55Pd30RE15 alloys by replacing Sc with other rare-earth elements (REs) (RE = Y, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu). These approximants, which have relatively small lattice constants and consequently smaller RE–RE distances compared with those for other RE-containing Tsai-type approximants, may be candidates for materials with novel electronic and magnetic properties similar to those observed in Au-based quasicrystals and approximants." @default.
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- W2898857922 date "2018-07-03" @default.
- W2898857922 modified "2023-10-01" @default.
- W2898857922 title "Formation of Ga–Pd–Sc icosahedral quasicrystal and approximant phases" @default.
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- W2898857922 doi "https://doi.org/10.1080/09500839.2018.1538578" @default.
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