FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2898885372> ?p ?o ?g. }

• W2898885372 endingPage "85" @default.
• W2898885372 startingPage "49" @default.
• W2898885372 abstract "The oxidation budget of the tropospheric gas phase is relatively well known. However, the concentrations and turnover rates of important oxidants such as OH that are present in the tropospheric aqueous phase are considerably more uncertain, as a result of the higher complexity of associated multiphase chemical interactions involved. This chapter outlines (i) the current understanding of the aqueous-phase OH oxidation budget, (ii) recent progress within the field with a focus on the uptake of highly oxidized organics as well as their effects on the oxidation capacity in aqueous aerosols, and (iii) future research objectives. In detail, the first part presents an overview on photochemical OH sinks and sources within the tropospheric aqueous phase, focusing on modelled and measured in-situ formation rates of OH. It also discusses current discrepancies between models and measurements as well as, finally, the limitations of both. In this part, model simulations using CAPRAM are presented. They demonstrate that utilizing a more detailed organic chemistry leads to substantially lowered aqueous-phase OH concentrations, more closely aligning modelled and measured OH concentrations. In the second part, a summary of current state-of-the-art knowledge on the role and fate of organic peroxides, labile hydroperoxides, and other organic peroxy species as potential OH sources is given. Furthermore, recent results of a model case study utilizing CAPRAM are presented, allowing an examination of the uptake and chemistry of highly oxidized organics from the gas phase and its effects. The case study demonstrates that the uptake and subsequent decomposition of labile hydroperoxides may lead to a mean increase of 19% of the aqueous OH sink and source rates. Finally, a brief perspective is given, including an outline of current gaps within the knowledge on the oxidation budget in aqueous aerosols as well as research objectives for future laboratory, field and model investigations." @default.
• W2898885372 created "2018-11-09" @default.
• W2898885372 creator A5003239040 @default.
• W2898885372 creator A5024951130 @default.
• W2898885372 date "2018-01-01" @default.
• W2898885372 modified "2023-10-16" @default.
• W2898885372 title "Tropospheric Aqueous-Phase OH Oxidation Chemistry: Current Understanding, Uptake of Highly Oxidized Organics and Its Effects" @default.
• W2898885372 cites W1566373779 @default.
• W2898885372 cites W1902682689 @default.
• W2898885372 cites W1965775902 @default.
• W2898885372 cites W1966570261 @default.
• W2898885372 cites W1970652095 @default.
• W2898885372 cites W1972989153 @default.
• W2898885372 cites W1974706428 @default.
• W2898885372 cites W1975585929 @default.
• W2898885372 cites W1980934066 @default.
• W2898885372 cites W1982711084 @default.
• W2898885372 cites W1985293027 @default.
• W2898885372 cites W1988657737 @default.
• W2898885372 cites W1990153941 @default.
• W2898885372 cites W2001313939 @default.
• W2898885372 cites W2001964759 @default.
• W2898885372 cites W2003557505 @default.
• W2898885372 cites W2007649442 @default.
• W2898885372 cites W2022252372 @default.
• W2898885372 cites W2026337722 @default.
• W2898885372 cites W2027099273 @default.
• W2898885372 cites W2027809325 @default.
• W2898885372 cites W2029783033 @default.
• W2898885372 cites W2029931639 @default.
• W2898885372 cites W2032848139 @default.
• W2898885372 cites W2034716589 @default.
• W2898885372 cites W2035671657 @default.
• W2898885372 cites W2036413039 @default.
• W2898885372 cites W2036463795 @default.
• W2898885372 cites W2042130089 @default.
• W2898885372 cites W2045845165 @default.
• W2898885372 cites W2047214935 @default.
• W2898885372 cites W2049190980 @default.
• W2898885372 cites W2051611630 @default.
• W2898885372 cites W2053029556 @default.
• W2898885372 cites W2057594098 @default.
• W2898885372 cites W2061444405 @default.
• W2898885372 cites W2061978475 @default.
• W2898885372 cites W2062316137 @default.
• W2898885372 cites W2062619462 @default.
• W2898885372 cites W2063735953 @default.
• W2898885372 cites W2066411725 @default.
• W2898885372 cites W2076335579 @default.
• W2898885372 cites W2077597619 @default.
• W2898885372 cites W2078357091 @default.
• W2898885372 cites W2081138937 @default.
• W2898885372 cites W2082242572 @default.
• W2898885372 cites W2090819943 @default.
• W2898885372 cites W2091642983 @default.
• W2898885372 cites W2094624914 @default.
• W2898885372 cites W2095410281 @default.
• W2898885372 cites W2097806302 @default.
• W2898885372 cites W2103073612 @default.
• W2898885372 cites W2105569336 @default.
• W2898885372 cites W2105711982 @default.
• W2898885372 cites W2110481067 @default.
• W2898885372 cites W2111102360 @default.
• W2898885372 cites W2111275491 @default.
• W2898885372 cites W2114837250 @default.
• W2898885372 cites W2116507044 @default.
• W2898885372 cites W2122054302 @default.
• W2898885372 cites W2123339760 @default.
• W2898885372 cites W2127754110 @default.
• W2898885372 cites W2141970008 @default.
• W2898885372 cites W2151195025 @default.
• W2898885372 cites W2151974479 @default.
• W2898885372 cites W2153201520 @default.
• W2898885372 cites W2154191515 @default.
• W2898885372 cites W2155704085 @default.
• W2898885372 cites W2157427270 @default.
• W2898885372 cites W2158540706 @default.
• W2898885372 cites W2163361418 @default.
• W2898885372 cites W2263056818 @default.
• W2898885372 cites W2286748995 @default.
• W2898885372 cites W2290108081 @default.
• W2898885372 cites W2298456115 @default.
• W2898885372 cites W2322712737 @default.
• W2898885372 cites W2330189997 @default.
• W2898885372 cites W2437571028 @default.
• W2898885372 cites W2511217667 @default.
• W2898885372 cites W2527266472 @default.
• W2898885372 cites W2530428864 @default.
• W2898885372 cites W2531558373 @default.
• W2898885372 cites W2550943717 @default.
• W2898885372 cites W2552325207 @default.
• W2898885372 cites W2622931167 @default.
• W2898885372 cites W2753565591 @default.
• W2898885372 cites W2784180476 @default.
• W2898885372 cites W2797935180 @default.
• W2898885372 cites W369801575 @default.
• W2898885372 cites W4241788311 @default.
• W2898885372 doi "https://doi.org/10.1021/bk-2018-1299.ch004" @default.

• next