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• W2898934293 abstract "Here, a combined experimental and theoretical investigation of the properties of Ni${}_{3}$TeO${}_{6}$ under pressure reveals reduced compressibility near 4 GPa due to the unique behavior of one bond angle. This trend arises from a nearby cavity in the crystal structure that enhances tunability in this and other corrundumlike materials. Analysis of superexchange angles reveals enhanced antiferromagnetic interactions, in line with an increase in ${T}_{N}$ observed in magnetization. Magnetoelectric coupling likely enhances polarization under pressure. This work suggests that incorporating empty cavities into crystal structures provides a new route for control of multiferroic properties." @default.
• W2898934293 created "2018-11-09" @default.
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• W2898934293 date "2018-11-01" @default.
• W2898934293 modified "2023-10-06" @default.
• W2898934293 title "High-pressure spectroscopic investigation of multiferroic <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msub><mml:mi>Ni</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi>TeO</mml:mi><mml:mn>6</mml:mn></mml:msub></mml:mrow></mml:math>" @default.
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• W2898934293 doi "https://doi.org/10.1103/physrevb.98.184101" @default.
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