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- W2899001738 abstract "A facile, transition-metal-free, and direct decarboxylative arylation of 2-picolinic acids with simple arenes is described. The oxidative decarboxylative arylation of 2-picolinic acids with arenes proceeds readily via N-chloro carbene intermediates to afford 2-arylpyridines in satisfactory to good yields under transition-metal-free conditions. This new type of decarboxylative arylation is operationally simple and scalable and exhibits high functional-group tolerance. Various synthetically useful functional groups, such as halogen atoms, methoxycarbonyl, and nitro, remain intact during the decarboxylative arylation of 2-picolinic acids." @default.
- W2899001738 created "2018-11-09" @default.
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- W2899001738 date "2018-11-02" @default.
- W2899001738 modified "2023-10-14" @default.
- W2899001738 title "Transition-Metal-Free Decarboxylative Arylation of 2-Picolinic Acids with Arenes under Air Conditions" @default.
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- W2899001738 doi "https://doi.org/10.1021/acs.orglett.8b03043" @default.
- W2899001738 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30388020" @default.
- W2899001738 hasPublicationYear "2018" @default.
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