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- W2899008872 endingPage "2778" @default.
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- W2899008872 abstract "An intriguing DABCO-catalyzed and DBU-promoted one-pot synthesis of an important class of (2-hydroxyaryl)pyridine derivatives bearing a carboxylate or a nitrile group suitably placed at C3 position of the aza-ring has been achieved in acceptable chemical yields with a broad functional group tolerance. This sequential C-C/C-N bond making process proceeds through a regioselective allylic alkylation/aza-Michael reaction between MBH carbonates derived from an acrylate/acrylonitrile and N-sulfonyl ketimines as C,N-binucleophiles catalyzed by DABCO, followed by elimination of SO2 under the influence of base and subsequent aromatization in an open atmosphere." @default.
- W2899008872 created "2018-11-09" @default.
- W2899008872 creator A5001546272 @default.
- W2899008872 creator A5043023763 @default.
- W2899008872 creator A5055421585 @default.
- W2899008872 creator A5055702136 @default.
- W2899008872 date "2018-11-02" @default.
- W2899008872 modified "2023-10-16" @default.
- W2899008872 title "DABCO- and DBU-promoted one-pot reaction of <i>N</i>-sulfonyl ketimines with Morita–Baylis–Hillman carbonates: a sequential approach to (2-hydroxyaryl)nicotinate derivatives" @default.
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- W2899008872 doi "https://doi.org/10.3762/bjoc.14.254" @default.
- W2899008872 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6244423" @default.
- W2899008872 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30498526" @default.
- W2899008872 hasPublicationYear "2018" @default.
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