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- W2899156928 abstract "The work herein presented, embraces various aspects of gold chemistry: the documentation of novel [alkynyl(triphenylphosphine)gold(I)] complexes carrying differently substituted propargylic amines and their pharmacological investigation on a series of cancer cell lines and the investigation of the dearomative cycloaddition reaction of indoles with electron-rich allenes catalysed by commercially available gold(I) complexes that show competence in performing the chemo-, regio- and diastereoselective formal [2+2]-cycloaddition between a wide range of substrates under mild conditions. It has also been developed the combined efficiency of Bu4N+ and F− ions in performing a cascade sequence involving intramolecular hydroamination of the C–C triple bond, cleavage of silyl-protecting groups and site-selective sigmatropic aza-Cope-type [3,3]-rearrangement." @default.
- W2899156928 created "2018-11-09" @default.
- W2899156928 creator A5039210662 @default.
- W2899156928 date "2018-05-09" @default.
- W2899156928 modified "2023-09-23" @default.
- W2899156928 title "Novel insights into gold(I) chemistry: from anticancer activity to new synthetic methodologies." @default.
- W2899156928 doi "https://doi.org/10.6092/unibo/amsdottorato/8597" @default.
- W2899156928 hasPublicationYear "2018" @default.
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