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- W2899163935 abstract "Three 1‐methyl‐4,4′‐bipyridinium (MQ + )‐based complexes, {[Cd(MQ)( p ‐BDC)Br]⋅H 2 O} n ( 1 ), {[Cd(MQ)( m ‐BDC)(H 2 O)Br]⋅3H 2 O} n ( 2 ) and Cu(MQ)Br 2 ( 3 ) ( p ‐H 2 BDC = 1,4‐benzenedicarboxylic acid, m ‐H 2 BDC = 1,3‐benzenedicarboxylic acid), have been synthesized and structurally characterized. Compounds 1 and 2 are one‐dimensional coordination polymers constituted of one coordinated MQ + cation, one coordinated Br − ion and chains of Cd 2+ ions connected by deprotonated BDC 2− units, which both have photochromism but different decolorization behaviors. The structures and photoresponsive behaviors controlled by auxiliary ligands have been explored. Compound 3 is constituted of one Cu + center, one MQ + ligand and two coordinated Br − ions in a ‘V’ configuration, exhibiting no photochromism." @default.
- W2899163935 created "2018-11-09" @default.
- W2899163935 creator A5062137862 @default.
- W2899163935 date "2018-10-29" @default.
- W2899163935 modified "2023-09-26" @default.
- W2899163935 title "Photochromism and decolorization controlled by auxiliary ligands of complexes derived from 1-methyl-4,4′-bipyridinium cation" @default.
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- W2899163935 doi "https://doi.org/10.1002/aoc.4578" @default.
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