Matches in SemOpenAlex for { <https://semopenalex.org/work/W2899173223> ?p ?o ?g. }
- W2899173223 endingPage "22" @default.
- W2899173223 startingPage "15" @default.
- W2899173223 abstract "Abstract The reactions of copper, silver, and gold with the imidazolium‐based polyhalide ionic liquid (IL) [C 6 C 1 Im][Br 2 I] were investigated by using X‐ray photoelectron spectroscopy (XPS), weight‐loss measurements, and gas‐phase mass spectrometry. All three Group 11 metals are strongly corroded by the IL at moderate temperatures to give a very high content of dissolved Cu I , Ag I , and Au I species. The IL–metal solutions are stable against contact with water and air. The replacement of imidazolium with inorganic sodium cations decreased metal corrosion rates by orders of magnitude. Our results clearly indicate metal oxidation by iodide from dibromoiodide anions to form molecular iodine and anionic [Br‐M I ‐Br] − (M=Cu, Ag, Au) complexes stabilized by imidazolium counterions. From experiments with a trihalide IL with imidazolium methylated at the 2‐position, we ruled out the formation of imidazole–carbene as a cause of the observed corrosion. In contrast to Group 11 metals, molybdenum is inert against the trihalide IL, which is attributed to surface passivation." @default.
- W2899173223 created "2018-11-09" @default.
- W2899173223 creator A5001718718 @default.
- W2899173223 creator A5035111702 @default.
- W2899173223 creator A5075116946 @default.
- W2899173223 creator A5076145514 @default.
- W2899173223 creator A5083631662 @default.
- W2899173223 date "2018-10-31" @default.
- W2899173223 modified "2023-10-09" @default.
- W2899173223 title "Reactions of a Polyhalide Ionic Liquid with Copper, Silver, and Gold" @default.
- W2899173223 cites W1963558230 @default.
- W2899173223 cites W1964364744 @default.
- W2899173223 cites W1965546620 @default.
- W2899173223 cites W1974162399 @default.
- W2899173223 cites W1980216394 @default.
- W2899173223 cites W1997110817 @default.
- W2899173223 cites W2002881973 @default.
- W2899173223 cites W2005907422 @default.
- W2899173223 cites W2026915696 @default.
- W2899173223 cites W2027316392 @default.
- W2899173223 cites W2034217755 @default.
- W2899173223 cites W2038035693 @default.
- W2899173223 cites W2048164835 @default.
- W2899173223 cites W2049061370 @default.
- W2899173223 cites W2049155105 @default.
- W2899173223 cites W2050366006 @default.
- W2899173223 cites W2054242917 @default.
- W2899173223 cites W2060118706 @default.
- W2899173223 cites W2068067410 @default.
- W2899173223 cites W2073322665 @default.
- W2899173223 cites W2083464707 @default.
- W2899173223 cites W2090425766 @default.
- W2899173223 cites W2116327492 @default.
- W2899173223 cites W2120517672 @default.
- W2899173223 cites W2122250145 @default.
- W2899173223 cites W2127031980 @default.
- W2899173223 cites W2136172160 @default.
- W2899173223 cites W2149317302 @default.
- W2899173223 cites W2168387226 @default.
- W2899173223 cites W2305915863 @default.
- W2899173223 cites W2610255239 @default.
- W2899173223 cites W2611562371 @default.
- W2899173223 cites W2950762742 @default.
- W2899173223 cites W2952523209 @default.
- W2899173223 cites W4235574122 @default.
- W2899173223 cites W4249891609 @default.
- W2899173223 cites W4382581876 @default.
- W2899173223 cites W4382584003 @default.
- W2899173223 doi "https://doi.org/10.1002/open.201800149" @default.
- W2899173223 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6317927" @default.
- W2899173223 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30622879" @default.
- W2899173223 hasPublicationYear "2018" @default.
- W2899173223 type Work @default.
- W2899173223 sameAs 2899173223 @default.
- W2899173223 citedByCount "13" @default.
- W2899173223 countsByYear W28991732232019 @default.
- W2899173223 countsByYear W28991732232020 @default.
- W2899173223 countsByYear W28991732232021 @default.
- W2899173223 countsByYear W28991732232022 @default.
- W2899173223 countsByYear W28991732232023 @default.
- W2899173223 crossrefType "journal-article" @default.
- W2899173223 hasAuthorship W2899173223A5001718718 @default.
- W2899173223 hasAuthorship W2899173223A5035111702 @default.
- W2899173223 hasAuthorship W2899173223A5075116946 @default.
- W2899173223 hasAuthorship W2899173223A5076145514 @default.
- W2899173223 hasAuthorship W2899173223A5083631662 @default.
- W2899173223 hasBestOaLocation W28991732231 @default.
- W2899173223 hasConcept C127413603 @default.
- W2899173223 hasConcept C154881586 @default.
- W2899173223 hasConcept C161790260 @default.
- W2899173223 hasConcept C171560689 @default.
- W2899173223 hasConcept C175708663 @default.
- W2899173223 hasConcept C178790620 @default.
- W2899173223 hasConcept C179104552 @default.
- W2899173223 hasConcept C185592680 @default.
- W2899173223 hasConcept C2776024174 @default.
- W2899173223 hasConcept C2778870691 @default.
- W2899173223 hasConcept C2779227376 @default.
- W2899173223 hasConcept C2780874372 @default.
- W2899173223 hasConcept C33574316 @default.
- W2899173223 hasConcept C42360764 @default.
- W2899173223 hasConcept C544153396 @default.
- W2899173223 hasConcept C544778455 @default.
- W2899173223 hasConcept C549387045 @default.
- W2899173223 hasConceptScore W2899173223C127413603 @default.
- W2899173223 hasConceptScore W2899173223C154881586 @default.
- W2899173223 hasConceptScore W2899173223C161790260 @default.
- W2899173223 hasConceptScore W2899173223C171560689 @default.
- W2899173223 hasConceptScore W2899173223C175708663 @default.
- W2899173223 hasConceptScore W2899173223C178790620 @default.
- W2899173223 hasConceptScore W2899173223C179104552 @default.
- W2899173223 hasConceptScore W2899173223C185592680 @default.
- W2899173223 hasConceptScore W2899173223C2776024174 @default.
- W2899173223 hasConceptScore W2899173223C2778870691 @default.
- W2899173223 hasConceptScore W2899173223C2779227376 @default.
- W2899173223 hasConceptScore W2899173223C2780874372 @default.
- W2899173223 hasConceptScore W2899173223C33574316 @default.
- W2899173223 hasConceptScore W2899173223C42360764 @default.